Synthesis and structure of tris(4-fluorophenylantimony) dicarboxylates: (4-FC 6 H 4 ) 3 Sb[OC(O)R] 2 , R = CH 2 I, C 6 F 5

V. V. Sharutin; O. K. Sharutina

doi:10.1007/s11172-017-1796-6

Synthesis and structure of tris(4-fluorophenylantimony) dicarboxylates: (4-FC₆H₄)₃Sb[OC(O)R]₂, R = CH₂I, C₆F₅

Authors: Sharutin V.V.¹, Sharutina O.K.¹
Affiliations:
1. South Ural State University (NRI)
Issue: Vol 66, No 4 (2017)
Pages: 707-710
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/240463
DOI: https://doi.org/10.1007/s11172-017-1796-6
ID: 240463

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Abstract
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Abstract

Tris(4-fluorophenyl)antimony reacts with iodoacetic and pentafluorobenzoic acids in the presence of tert-butylhydroperoxide to give tris(4-fluorophenyl)antimony bis(iodoacetate) and tris(4-fluorophenyl)antimony bis(pentafluorobenzoate), respectively. Structures of organoantimony compounds were established by ¹H and ¹⁹F NMR spectroscopy and X-ray diffraction analysis.

About the authors

V. V. Sharutin

South Ural State University (NRI)

Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. Lenina, Chelyabinsk, 454080

O. K. Sharutina