Email this article Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst
- Authors: Mironenko R.M.1,2, Belskaya O.B.1,3, Lavrenov A.V.1, Likholobov V.A.1,3,4
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Affiliations:
- Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences
- Dostoevsky Omsk State University
- Omsk State Technical University
- Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 66, No 4 (2017)
- Pages: 673-676
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240407
- DOI: https://doi.org/10.1007/s11172-017-1790-z
- ID: 240407
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Abstract
The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueous-phase hydrogenation of furfural. Under the chosen reaction conditions (temperature of 473 K, total pressure of 8 MPa), the selectivity towards cyclopentanol reaches 77% at a complete conversion of furfural. A high activity of this catalyst can be associated with changes in the electronic state and dispersion of the supported metals caused by their mutual interaction and formation of PdRu alloy.
About the authors
R. M. Mironenko
Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Dostoevsky Omsk State University
Author for correspondence.
Email: ch-mrm@mail.ru
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040; 55a prosp. Mira, Omsk, 644077
O. B. Belskaya
Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Omsk State Technical University
Email: ch-mrm@mail.ru
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040; 11 prosp. Mira, Omsk, 644050
A. V. Lavrenov
Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences
Email: ch-mrm@mail.ru
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040
V. A. Likholobov
Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Omsk State Technical University; Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences
Email: ch-mrm@mail.ru
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040; 11 prosp. Mira, Omsk, 644050; 15 prosp. Marksa, Omsk, 644024
