Ambiguousness of GC-MS identification of spiro[2.4]hepta-4,6-diene in natural objects
- Authors: Menchikov L.G.1, Nefedov O.M.1, Zenkevich I.G.2
-
Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Department of Chemistry, St. Petersburg State University
- Issue: Vol 66, No 3 (2017)
- Pages: 491-496
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240204
- DOI: https://doi.org/10.1007/s11172-017-1761-4
- ID: 240204
Cite item
Abstract
The publications on the GC-MS identification of spiro[2.4]hepta-4,6-diene in various natural objects were critically considered. Significant similarity of the mass spectra and coincidence of the GC retention indices on standard nonpolar phases of spiro[2.4]hepta-4,6-diene (761±3) and its isomer (toluene, 760±8) do not allow one to assert that the spirocyclic hydrocarbon was found in all the cases. Additional analytical parameters should be applied to differentiate such isomers.
About the authors
L. G. Menchikov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: mlg@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
O. M. Nefedov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: mlg@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
I. G. Zenkevich
Department of Chemistry, St. Petersburg State University
Email: mlg@ioc.ac.ru
Russian Federation, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504