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Ambiguousness of GC-MS identification of spiro[2.4]hepta-4,6-diene in natural objects


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The publications on the GC-MS identification of spiro[2.4]hepta-4,6-diene in various natural objects were critically considered. Significant similarity of the mass spectra and coincidence of the GC retention indices on standard nonpolar phases of spiro[2.4]hepta-4,6-diene (761±3) and its isomer (toluene, 760±8) do not allow one to assert that the spirocyclic hydrocarbon was found in all the cases. Additional analytical parameters should be applied to differentiate such isomers.

作者简介

L. Menchikov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: mlg@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991

O. Nefedov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: mlg@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991

I. Zenkevich

Department of Chemistry, St. Petersburg State University

Email: mlg@ioc.ac.ru
俄罗斯联邦, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504

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