Email this article First coordination polymer based on diterpenoids. Synthesis, structure, and magnetic properties
- Authors: Kataeva O.N.1, Mamedova V.L.1, Nikitina K.A.1, Metlushka K.E.1, Ivshin K.A.2, Krupskaya Y.V.3, Kataev V.E.3, Sinyashin O.G.1, Alfonsov V.A.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- A. M. Butlerov Chemical Institute of Kazan (Volga Region) Federal University
- Institute for Solid and Materials Research
- Issue: Vol 66, No 2 (2017)
- Pages: 362-367
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240090
- DOI: https://doi.org/10.1007/s11172-017-1741-8
- ID: 240090
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Abstract
One-dimensional coordination polymer was obtained by cation exchange reaction of triethylammonium salt of methyl ent-16α-H-phosphonyloxybeyeran-19-oate with CuCl2. Its structure was determined by single crystal X-ray diffraction analysis. The formation of hydrophilic channels consisting of phosphorus containing fragments, copper atoms, and water, which are framed by hydrophobic surroundings from tetracyclic bulky beyeran substituents, is observed in the crystal. The study of the temperature dependence of the static magnetic susceptibility of the polymer indicates a weak antiferromagnetic interaction between the copper spins.
About the authors
O. N. Kataeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. L. Mamedova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
K. A. Nikitina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
K. E. Metlushka
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
K. A. Ivshin
A. M. Butlerov Chemical Institute of Kazan (Volga Region) Federal University
Email: alfonsov@yandex.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
Yu. V. Krupskaya
Institute for Solid and Materials Research
Email: alfonsov@yandex.ru
Germany, 20 Helmholtzstrasse, Dresden, 01069
V. E. Kataev
Institute for Solid and Materials Research
Email: alfonsov@yandex.ru
Germany, 20 Helmholtzstrasse, Dresden, 01069
O. G. Sinyashin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. A. Alfonsov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Author for correspondence.
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
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