First coordination polymer based on diterpenoids. Synthesis, structure, and magnetic properties
- 作者: Kataeva O.1, Mamedova V.1, Nikitina K.1, Metlushka K.1, Ivshin K.2, Krupskaya Y.3, Kataev V.3, Sinyashin O.1, Alfonsov V.1
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隶属关系:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- A. M. Butlerov Chemical Institute of Kazan (Volga Region) Federal University
- Institute for Solid and Materials Research
- 期: 卷 66, 编号 2 (2017)
- 页面: 362-367
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240090
- DOI: https://doi.org/10.1007/s11172-017-1741-8
- ID: 240090
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详细
One-dimensional coordination polymer was obtained by cation exchange reaction of triethylammonium salt of methyl ent-16α-H-phosphonyloxybeyeran-19-oate with CuCl2. Its structure was determined by single crystal X-ray diffraction analysis. The formation of hydrophilic channels consisting of phosphorus containing fragments, copper atoms, and water, which are framed by hydrophobic surroundings from tetracyclic bulky beyeran substituents, is observed in the crystal. The study of the temperature dependence of the static magnetic susceptibility of the polymer indicates a weak antiferromagnetic interaction between the copper spins.
作者简介
O. Kataeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Mamedova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
K. Nikitina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
K. Metlushka
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
K. Ivshin
A. M. Butlerov Chemical Institute of Kazan (Volga Region) Federal University
Email: alfonsov@yandex.ru
俄罗斯联邦, 18 ul. Kremlevskaya, Kazan, 420008
Yu. Krupskaya
Institute for Solid and Materials Research
Email: alfonsov@yandex.ru
德国, 20 Helmholtzstrasse, Dresden, 01069
V. Kataev
Institute for Solid and Materials Research
Email: alfonsov@yandex.ru
德国, 20 Helmholtzstrasse, Dresden, 01069
O. Sinyashin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Alfonsov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088