Hydroxyketones in the thiadiazine cycle formation
- Authors: Pulatov E.K.1, Isobaev M.J.1, Mavlonov B.G.1
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Affiliations:
- V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
- Issue: Vol 65, No 10 (2016)
- Pages: 2475-2478
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239187
- DOI: https://doi.org/10.1007/s11172-016-1609-3
- ID: 239187
Cite item
Abstract
Cyclocondensation of 1-hydroxyketones with thiosemicarbazide resulted in thiadiazines. Nitrate ester of 1-hydroxyketone reacted under similar conditions to give the corresponding thiosemicarbazone. In the case of bromoacetyl-substituted nitrate ester of 1-hydroxyketone, condensation proceeded via intramolecular reaction between the thiol and bromomethyl groups.
About the authors
E. Kh. Pulatov
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Author for correspondence.
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, Dushanbe, 734063
M. J. Isobaev
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, Dushanbe, 734063
B. G. Mavlonov
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, Dushanbe, 734063