Email this article Complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide: structure, aggregation, and biological activity
- Authors: Zhil´tsova E.P.1, Ibatullina M.R.1,2, Lukashenko S.S.1, Pashirova T.N.1, Voloshina A.D.1, Zobov V.V.1, Ziganshina S.A.3, Kutyreva M.P.2, Zakharova L.Y.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
- A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
- E. K. Zavoisky Kazan Physical Technical Institute, Kazan Scientific Center, Russian Academy of Sciences
- Issue: Vol 65, No 5 (2016)
- Pages: 1365-1371
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238317
- DOI: https://doi.org/10.1007/s11172-016-1463-3
- ID: 238317
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Abstract
The aggregation and adsorption properties of a new complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide were studied by methods of conductometry, tensiometry, and dynamic light scattering. The critical micelle concentration, size of the aggregates, and adsorption characteristics at the water—air interface were determined. The antimicrobial and antifungal effects were established. The studied properties of the complex were compared with the properties of the ligand and cationic surfactants with a head group of the cyclic and acyclic types. The enhanced aggregation ability of the complex and its improved biological activity were shown.
About the authors
E. P. Zhil´tsova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Author for correspondence.
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
M. R. Ibatullina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences; A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008
S. S. Lukashenko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
T. N. Pashirova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
A. D. Voloshina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. V. Zobov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
S. A. Ziganshina
E. K. Zavoisky Kazan Physical Technical Institute, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Russian Federation, 10/7 ul. Sibirsky trakt, Kazan, 420029
M. P. Kutyreva
A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Email: zhiltsova@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
L. Ya. Zakharova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
