Complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide: structure, aggregation, and biological activity
- Авторы: Zhil´tsova E.1, Ibatullina M.1,2, Lukashenko S.1, Pashirova T.1, Voloshina A.1, Zobov V.1, Ziganshina S.3, Kutyreva M.2, Zakharova L.1
-
Учреждения:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
- A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
- E. K. Zavoisky Kazan Physical Technical Institute, Kazan Scientific Center, Russian Academy of Sciences
- Выпуск: Том 65, № 5 (2016)
- Страницы: 1365-1371
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238317
- DOI: https://doi.org/10.1007/s11172-016-1463-3
- ID: 238317
Цитировать
Аннотация
The aggregation and adsorption properties of a new complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide were studied by methods of conductometry, tensiometry, and dynamic light scattering. The critical micelle concentration, size of the aggregates, and adsorption characteristics at the water—air interface were determined. The antimicrobial and antifungal effects were established. The studied properties of the complex were compared with the properties of the ligand and cationic surfactants with a head group of the cyclic and acyclic types. The enhanced aggregation ability of the complex and its improved biological activity were shown.
Об авторах
E. Zhil´tsova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
M. Ibatullina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences; A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008
S. Lukashenko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
T. Pashirova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
A. Voloshina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Zobov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
S. Ziganshina
E. K. Zavoisky Kazan Physical Technical Institute, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Россия, 10/7 ul. Sibirsky trakt, Kazan, 420029
M. Kutyreva
A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University
Email: zhiltsova@iopc.ru
Россия, 18 ul. Kremlevskaya, Kazan, 420008
L. Zakharova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: zhiltsova@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088