Molecular and crystal structure of 19-nor-4α(6-hydrazonocarbonyl-3,4,5-trihydroxytetrahydropyran-2-oxycarbonyl)-16-hydrazono-ent-beyeran
- Authors: Dobrynin A.B.1, Andreeva O.V.1, Litvinov I.A.1, Kataev V.E.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Issue: Vol 65, No 5 (2016)
- Pages: 1332-1335
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238225
- DOI: https://doi.org/10.1007/s11172-016-1457-1
- ID: 238225
Cite item
Abstract
X-ray crystallography was used to study molecular and crystal structure of 19-nor-4α-(6-hydrazonocarbonyl-3,4,5-trihydroxytetrahydropyran-2-oxycarbonyl)-16-hydrazono-ent-beyeran (1). The bulky hydrophilic substituents are on one side of the hydrophobic beyeran fragment, that leads to the layer-type crystal packing: the hydrophilic layers, in which molecules 1 and hydrate water molecules bound by the classic hydrogen bonds of the O—H...O—and N—H...O type alternate with hydrophobic layers formed by the ent-beyeran fragments.
About the authors
A. B. Dobrynin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Author for correspondence.
Email: aldo@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
O. V. Andreeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: aldo@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
I. A. Litvinov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: aldo@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. E. Kataev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: aldo@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088