Email this article Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid
- Authors: Lagodzinskaya G.V.1, Laptinskaya T.V.2, Kazakov A.I.1, Kurochkina L.S.1, Manelis G.B.1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Department of Physics, M. V. Lomonosov Moscow State University
- Issue: Vol 65, No 4 (2016)
- Pages: 984-992
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237787
- DOI: https://doi.org/10.1007/s11172-016-1401-4
- ID: 237787
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Abstract
Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.
About the authors
G. V. Lagodzinskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: gvl@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
T. V. Laptinskaya
Department of Physics, M. V. Lomonosov Moscow State University
Email: gvl@icp.ac.ru
Russian Federation, Build. 2, 1 Leninskie Gory, Moscow, 119991
A. I. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. S. Kurochkina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. B. Manelis
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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