Enviar artigo por via de e-mail Slow large-scale supramolecular structuring as a cause of kinetic anomalies in the liquid-phase oxidation with nitric acid
- Autores: Lagodzinskaya G.V.1, Laptinskaya T.V.2, Kazakov A.I.1, Kurochkina L.S.1, Manelis G.B.1
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Afiliações:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Department of Physics, M. V. Lomonosov Moscow State University
- Edição: Volume 65, Nº 4 (2016)
- Páginas: 984-992
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237787
- DOI: https://doi.org/10.1007/s11172-016-1401-4
- ID: 237787
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Resumo
Isothermal calorimetry, static and dynamic light scattering, and NMR spectroscopy studies provided evidence for slow formation of large associates of solvates in aqueous solutions of nitric acid, which makes it possible to attribute the anomalous kinetic features in the oxidation of acetone to the supramolecular mechanism of the reaction.
Sobre autores
G. Lagodzinskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Autor responsável pela correspondência
Email: gvl@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
T. Laptinskaya
Department of Physics, M. V. Lomonosov Moscow State University
Email: gvl@icp.ac.ru
Rússia, Build. 2, 1 Leninskie Gory, Moscow, 119991
A. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. Kurochkina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Manelis
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gvl@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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