Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer
- Авторы: Krichen F.1, Walha S.1, Kabadou A.1
-
Учреждения:
- Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
- Выпуск: Том 62, № 7 (2017)
- Страницы: 1152-1156
- Раздел: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/192013
- DOI: https://doi.org/10.1134/S1063774517070148
- ID: 192013
Цитировать
Аннотация
A new mixed-valence coordination polymer [Cu3(SCN)4(DMSO)2]n (SCN– = thiocyanato and DMSO = dimethyl sulfoxide) was prepared and characterized by single crystal X-ray diffraction method. The in situ formation of thiocyanate during the synthesis induces reduction of a part of Cu(II) to Cu(I). The three-dimensional structure of the binuclear thiocyanato bridged compound provided an example of pseudohalide materials containing two different environments for both copper centers.
Об авторах
Firas Krichen
Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
Автор, ответственный за переписку.
Email: firas.krichen@yahoo.com
Тунис, Sfax
Siwar Walha
Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
Email: firas.krichen@yahoo.com
Тунис, Sfax
Ahlem Kabadou
Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
Email: firas.krichen@yahoo.com
Тунис, Sfax
Дополнительные файлы
