Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer
- Authors: Krichen F.1, Walha S.1, Kabadou A.1
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Affiliations:
- Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
- Issue: Vol 62, No 7 (2017)
- Pages: 1152-1156
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/192013
- DOI: https://doi.org/10.1134/S1063774517070148
- ID: 192013
Cite item
Abstract
A new mixed-valence coordination polymer [Cu3(SCN)4(DMSO)2]n (SCN– = thiocyanato and DMSO = dimethyl sulfoxide) was prepared and characterized by single crystal X-ray diffraction method. The in situ formation of thiocyanate during the synthesis induces reduction of a part of Cu(II) to Cu(I). The three-dimensional structure of the binuclear thiocyanato bridged compound provided an example of pseudohalide materials containing two different environments for both copper centers.
About the authors
Firas Krichen
Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
Author for correspondence.
Email: firas.krichen@yahoo.com
Tunisia, Sfax
Siwar Walha
Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
Email: firas.krichen@yahoo.com
Tunisia, Sfax
Ahlem Kabadou
Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
Email: firas.krichen@yahoo.com
Tunisia, Sfax
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