Single Crystal X-ray Study of 6-Phenyl-4-(p-tolyl)pyridin-2(1H)-one
- Autores: Khajuria R.1, Sharma S.2, Kapoor K.1, Gupta V.2
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Afiliações:
- Department of Chemistry
- X-ray Crystallography Laboratory, Department of Physics and Electronics
- Edição: Volume 62, Nº 7 (2017)
- Páginas: 1144-1147
- Seção: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191959
- DOI: https://doi.org/10.1134/S1063774517070227
- ID: 191959
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Resumo
The title compound 6-phenyl-4-(p-tolyl)pyridin-2(1H)-one was synthesized via one-pot, three component reaction of (E)-1-phenyl-3-(p-tolyl)-2-propen-1-one, ethyl 2-nitroacetate and ammonium acetate in refluxing ethanol, as a shiny green crystalline solid in 83% yield. Its structure was characterized by spectral studies and unambiguously corroborated by X-ray diffraction crystallography. The crystals of title compound are monoclinic, sp. gr. P21/n, a = 11.8346(7) Å, b = 13.4413(9) Å, c = 17.7626(10) Å, β = 99.479(5)°, and Z = 8. All the rings in molecule of the title compound are planar. Hydrogen interactions play significant role in stabilizing the crystal structure and the supramolecular aggregate of molecules is facilitated by strong N–H···O and C–H···O type of hydrogen interactions.
Sobre autores
Rajni Khajuria
Department of Chemistry
Email: vivek_gupta2k2@hotmail.com
Índia, Jammu and Kashmir, 180006
Suresh Sharma
X-ray Crystallography Laboratory, Department of Physics and Electronics
Email: vivek_gupta2k2@hotmail.com
Índia, Jammu and Kashmir, 180006
Kamal Kapoor
Department of Chemistry
Autor responsável pela correspondência
Email: kamalkka@gmail.com
Índia, Jammu and Kashmir, 180006
Vivek Gupta
X-ray Crystallography Laboratory, Department of Physics and Electronics
Autor responsável pela correspondência
Email: vivek_gupta2k2@hotmail.com
Índia, Jammu and Kashmir, 180006