Single Crystal X-ray Study of 6-Phenyl-4-(p-tolyl)pyridin-2(1H)-one
- Authors: Khajuria R.1, Sharma S.2, Kapoor K.K.1, Gupta V.K.2
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Affiliations:
- Department of Chemistry
- X-ray Crystallography Laboratory, Department of Physics and Electronics
- Issue: Vol 62, No 7 (2017)
- Pages: 1144-1147
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191959
- DOI: https://doi.org/10.1134/S1063774517070227
- ID: 191959
Cite item
Abstract
The title compound 6-phenyl-4-(p-tolyl)pyridin-2(1H)-one was synthesized via one-pot, three component reaction of (E)-1-phenyl-3-(p-tolyl)-2-propen-1-one, ethyl 2-nitroacetate and ammonium acetate in refluxing ethanol, as a shiny green crystalline solid in 83% yield. Its structure was characterized by spectral studies and unambiguously corroborated by X-ray diffraction crystallography. The crystals of title compound are monoclinic, sp. gr. P21/n, a = 11.8346(7) Å, b = 13.4413(9) Å, c = 17.7626(10) Å, β = 99.479(5)°, and Z = 8. All the rings in molecule of the title compound are planar. Hydrogen interactions play significant role in stabilizing the crystal structure and the supramolecular aggregate of molecules is facilitated by strong N–H···O and C–H···O type of hydrogen interactions.
About the authors
Rajni Khajuria
Department of Chemistry
Email: vivek_gupta2k2@hotmail.com
India, Jammu and Kashmir, 180006
Suresh Sharma
X-ray Crystallography Laboratory, Department of Physics and Electronics
Email: vivek_gupta2k2@hotmail.com
India, Jammu and Kashmir, 180006
Kamal K. Kapoor
Department of Chemistry
Author for correspondence.
Email: kamalkka@gmail.com
India, Jammu and Kashmir, 180006
Vivek K. Gupta
X-ray Crystallography Laboratory, Department of Physics and Electronics
Author for correspondence.
Email: vivek_gupta2k2@hotmail.com
India, Jammu and Kashmir, 180006