Molecular and crystal structure of 2-{(E)-[(4-Methylphenyl)imino]methyl}-4-nitrophenol: A redetermination
- Autores: Kaynar N.1, Tanak H.1, Şahin S.2, Dege N.1, Ağar E.2, Yavuz M.1
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Afiliações:
- Department of Physics, Faculty of Arts and Sciences
- Department of Chemistry, Faculty of Arts and Sciences
- Edição: Volume 61, Nº 2 (2016)
- Páginas: 239-242
- Seção: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/189858
- DOI: https://doi.org/10.1134/S1063774516020097
- ID: 189858
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Resumo
The crystal structure of the title compound, C14H12N2O3, was recently determined as a mixture of its neutral (OH containing) and zwitterionic (NH containing) forms, in a 0.60 (4): 0.40 (4) ratio using the X-ray determination. In this study, the title compound has been characterized by FT-IR and X-ray diffraction. The redetermination showed that the title compound has only enol (OH) form because of lack of the NH stretching vibration in FT-IR spectrum. In addition, the molecular structure and tautomerism of the title compound have been discussed.
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Sobre autores
Nihal Kaynar
Department of Physics, Faculty of Arts and Sciences
Autor responsável pela correspondência
Email: nihal_kan84@windowslive.com
Turquia, Samsun
Hasan Tanak
Department of Physics, Faculty of Arts and Sciences
Email: nihal_kan84@windowslive.com
Turquia, Samsun
Songul Şahin
Department of Chemistry, Faculty of Arts and Sciences
Email: nihal_kan84@windowslive.com
Turquia, Samsun
Necmi Dege
Department of Physics, Faculty of Arts and Sciences
Email: nihal_kan84@windowslive.com
Turquia, Samsun
Erbil Ağar
Department of Chemistry, Faculty of Arts and Sciences
Email: nihal_kan84@windowslive.com
Turquia, Samsun
Metin Yavuz
Department of Physics, Faculty of Arts and Sciences
Email: nihal_kan84@windowslive.com
Turquia, Samsun