Molecular and crystal structure of 2-{(E)-[(4-Methylphenyl)imino]methyl}-4-nitrophenol: A redetermination


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The crystal structure of the title compound, C14H12N2O3, was recently determined as a mixture of its neutral (OH containing) and zwitterionic (NH containing) forms, in a 0.60 (4): 0.40 (4) ratio using the X-ray determination. In this study, the title compound has been characterized by FT-IR and X-ray diffraction. The redetermination showed that the title compound has only enol (OH) form because of lack of the NH stretching vibration in FT-IR spectrum. In addition, the molecular structure and tautomerism of the title compound have been discussed.

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Nihal Kaynar

Department of Physics, Faculty of Arts and Sciences

编辑信件的主要联系方式.
Email: nihal_kan84@windowslive.com
土耳其, Samsun

Hasan Tanak

Department of Physics, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
土耳其, Samsun

Songul Şahin

Department of Chemistry, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
土耳其, Samsun

Necmi Dege

Department of Physics, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
土耳其, Samsun

Erbil Ağar

Department of Chemistry, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
土耳其, Samsun

Metin Yavuz

Department of Physics, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
土耳其, Samsun

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