Peculiarities of the Dielectric Spectra of Triglycine Sulfate Crystals with a Profile Distribution of Chromium


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Abstract

The temperature evolution of the dielectric spectra of TGS–TGS + Cr crystals (TGS stands for triglycine sulfate) with a periodic distribution of chromium impurity (Cr3+) has been studied in comparison with nominally pure TGS crystals in the frequency range from 10 to 107 Hz upon heating and cooling. It is shown that impurity crystals are characterized by the absence of dielectric dispersion in both measurement modes. An approach is proposed to explain the peculiarities of the dielectric dispersion of crystals with a periodic distribution of chromium impurity from the standpoint of mobile activity of certain elements of the TGS crystal structure.

About the authors

E. S. Ivanova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Author for correspondence.
Email: ivanova.el.ser@gmail.com
Russian Federation, Moscow, 119333

G. I. Ovchinnikova

Faculty of Physics, Moscow State University

Email: ivanova.el.ser@gmail.com
Russian Federation, Moscow

A. P. Eremeev

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences; Faculty of Physics, Moscow State University

Email: ivanova.el.ser@gmail.com
Russian Federation, Moscow, 119333; Moscow

V. V. Grebenev

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: ivanova.el.ser@gmail.com
Russian Federation, Moscow, 119333

N. V. Belugina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: ivanova.el.ser@gmail.com
Russian Federation, Moscow, 119333

A. L. Tolstikhina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: ivanova.el.ser@gmail.com
Russian Federation, Moscow, 119333


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