Peculiarities of the Dielectric Spectra of Triglycine Sulfate Crystals with a Profile Distribution of Chromium

Аннотация

The temperature evolution of the dielectric spectra of TGS–TGS + Cr crystals (TGS stands for triglycine sulfate) with a periodic distribution of chromium impurity (Cr³⁺) has been studied in comparison with nominally pure TGS crystals in the frequency range from 10 to 10⁷ Hz upon heating and cooling. It is shown that impurity crystals are characterized by the absence of dielectric dispersion in both measurement modes. An approach is proposed to explain the peculiarities of the dielectric dispersion of crystals with a periodic distribution of chromium impurity from the standpoint of mobile activity of certain elements of the TGS crystal structure.