Email this article Crystal Structure of Two V-shaped Ligands with N-Heterocycles
- Authors: Wang G.1, Sun S.1, Zhang X.2, Sun S.3
-
Affiliations:
- Department of Applied Chemistry
- MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering
- Department of Technology and Service
- Issue: Vol 62, No 7 (2017)
- Pages: 1113-1117
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191802
- DOI: https://doi.org/10.1134/S106377451707032X
- ID: 191802
Cite item
Open Access
Access granted
Subscription Access
Abstract
Two V-shaped ligands with N-heterocycles, bis(4-(1H-imidazol-1-yl) phenyl)methanone (1), and bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone (2) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. Crystal structures of 1 and 2 have been determined by X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. P21/c, Z = 4. The crystal of 2 is orthorhombic, sp. gr. Fdd2, Z = 8. X-ray diffraction analyses show that the V-shaped angles of 1 and 2 are 122.72(15)° and 120.7(4)°, respectively. Intermolecular C–H···O, C–H···N, C–H···π, and π···π interactions link the components into three-dimensional networks in the crystal structures.
About the authors
Gao-Feng Wang
Department of Applied Chemistry
Author for correspondence.
Email: wgf1979@126.com
China, Yuncheng
Shu-Wen Sun
Department of Applied Chemistry
Email: zhangx@hit.edu.cn
China, Yuncheng
Xiao Zhang
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering
Author for correspondence.
Email: zhangx@hit.edu.cn
China, Harbin, 150080, P. R.
Shu-Gang Sun
Department of Technology and Service
Email: zhangx@hit.edu.cn
China, Xichang
Supplementary files
