Crystal Structure of Two V-shaped Ligands with N-Heterocycles
- Авторлар: Wang G.1, Sun S.1, Zhang X.2, Sun S.3
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Мекемелер:
- Department of Applied Chemistry
- MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering
- Department of Technology and Service
- Шығарылым: Том 62, № 7 (2017)
- Беттер: 1113-1117
- Бөлім: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191802
- DOI: https://doi.org/10.1134/S106377451707032X
- ID: 191802
Дәйексөз келтіру
Аннотация
Two V-shaped ligands with N-heterocycles, bis(4-(1H-imidazol-1-yl) phenyl)methanone (1), and bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone (2) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. Crystal structures of 1 and 2 have been determined by X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. P21/c, Z = 4. The crystal of 2 is orthorhombic, sp. gr. Fdd2, Z = 8. X-ray diffraction analyses show that the V-shaped angles of 1 and 2 are 122.72(15)° and 120.7(4)°, respectively. Intermolecular C–H···O, C–H···N, C–H···π, and π···π interactions link the components into three-dimensional networks in the crystal structures.
Авторлар туралы
Gao-Feng Wang
Department of Applied Chemistry
Хат алмасуға жауапты Автор.
Email: wgf1979@126.com
ҚХР, Yuncheng
Shu-Wen Sun
Department of Applied Chemistry
Email: zhangx@hit.edu.cn
ҚХР, Yuncheng
Xiao Zhang
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering
Хат алмасуға жауапты Автор.
Email: zhangx@hit.edu.cn
ҚХР, Harbin, 150080, P. R.
Shu-Gang Sun
Department of Technology and Service
Email: zhangx@hit.edu.cn
ҚХР, Xichang
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