Отправить статью по E-mail Aquanitrilotris(methylenephosphonato)dirubidium [Rb2(H2O){μ12-NH(CH2PO3H)3}]: Synthesis and structure
- Авторы: Somov N.V.1, Chausov F.F.2,3,4, Zakirova R.M.3, Shumilova M.A.4, Aleksandrov V.A.4, Petrov V.G.4
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Учреждения:
- Lobachevsky State University of Nizhny Novgorod
- Physical–Technical Institute, Ural Branch
- Udmurt State University
- Institute of Mechanics, Ural Branch
- Выпуск: Том 62, № 5 (2017)
- Страницы: 734-738
- Раздел: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191300
- DOI: https://doi.org/10.1134/S1063774517050212
- ID: 191300
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Аннотация
Aquanitrilotris(methylenephosphonato)dirubidium is a 3D coordination polymer with a layer structure. Space group \(P\bar 1\), Z = 2; a = 8.0380(3) Å, b = 9.0522(4) Å, and c = 10.7837(4) Å; α = 113.252(4)°, β = 105.391(3)°, and γ = 96.182(3)°. Rb atoms populate two symmetrically inequivalent positions with c.n. = 8 and 10; significant difference in O–Rb–O angles in the coordination polyhedra is indicative of the ionic type of Rb–O bonds. In the crystal packing, molecules are connected by not only coordination bonds but hydrogen bonds as well.
Об авторах
N. Somov
Lobachevsky State University of Nizhny Novgorod
Автор, ответственный за переписку.
Email: somov@phys.unn.ru
Россия, Nizhny Novgorod, 603950
F. Chausov
Physical–Technical Institute, Ural Branch; Udmurt State University; Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
Россия, Izhevsk, 426000; Izhevsk, 426034; Izhevsk, 426067
R. Zakirova
Udmurt State University
Email: somov@phys.unn.ru
Россия, Izhevsk, 426034
M. Shumilova
Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
Россия, Izhevsk, 426067
V. Aleksandrov
Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
Россия, Izhevsk, 426067
V. Petrov
Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
Россия, Izhevsk, 426067
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