电邮这篇文章 Aquanitrilotris(methylenephosphonato)dirubidium [Rb2(H2O){μ12-NH(CH2PO3H)3}]: Synthesis and structure
- 作者: Somov N.V.1, Chausov F.F.2,3,4, Zakirova R.M.3, Shumilova M.A.4, Aleksandrov V.A.4, Petrov V.G.4
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隶属关系:
- Lobachevsky State University of Nizhny Novgorod
- Physical–Technical Institute, Ural Branch
- Udmurt State University
- Institute of Mechanics, Ural Branch
- 期: 卷 62, 编号 5 (2017)
- 页面: 734-738
- 栏目: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191300
- DOI: https://doi.org/10.1134/S1063774517050212
- ID: 191300
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详细
Aquanitrilotris(methylenephosphonato)dirubidium is a 3D coordination polymer with a layer structure. Space group \(P\bar 1\), Z = 2; a = 8.0380(3) Å, b = 9.0522(4) Å, and c = 10.7837(4) Å; α = 113.252(4)°, β = 105.391(3)°, and γ = 96.182(3)°. Rb atoms populate two symmetrically inequivalent positions with c.n. = 8 and 10; significant difference in O–Rb–O angles in the coordination polyhedra is indicative of the ionic type of Rb–O bonds. In the crystal packing, molecules are connected by not only coordination bonds but hydrogen bonds as well.
作者简介
N. Somov
Lobachevsky State University of Nizhny Novgorod
编辑信件的主要联系方式.
Email: somov@phys.unn.ru
俄罗斯联邦, Nizhny Novgorod, 603950
F. Chausov
Physical–Technical Institute, Ural Branch; Udmurt State University; Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
俄罗斯联邦, Izhevsk, 426000; Izhevsk, 426034; Izhevsk, 426067
R. Zakirova
Udmurt State University
Email: somov@phys.unn.ru
俄罗斯联邦, Izhevsk, 426034
M. Shumilova
Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
俄罗斯联邦, Izhevsk, 426067
V. Aleksandrov
Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
俄罗斯联邦, Izhevsk, 426067
V. Petrov
Institute of Mechanics, Ural Branch
Email: somov@phys.unn.ru
俄罗斯联邦, Izhevsk, 426067
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