Defect structure of TiS3 single crystals of the A-ZrSe3 type


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The defect structure of TiS3 single crystals of the A-ZrSe3 type has been determined based on X-ray diffraction data. Shear defects manifest themselves as displacements of ab layers (which can imitate a twin) by ∼0.5a. Regular shears facilitate the formation of a superstructure along the c axis. A model of defect in the layer structure is proposed to explain the atomic displacements at an angle to the layer plane.

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N. Bolotina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

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Email: nb_bolotina@mail.ru
俄罗斯联邦, Moscow, 119333

I. Gorlova

Kotel’nikov Institute of Radioengineering and Electronics

Email: nb_bolotina@mail.ru
俄罗斯联邦, Moscow, 125009

I. Verin

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: nb_bolotina@mail.ru
俄罗斯联邦, Moscow, 119333

A. Titov

Mikheev Institute of Metal Physics, Ural Branch

Email: nb_bolotina@mail.ru
俄罗斯联邦, Yekaterinburg, 620041

A. Arakcheeva

Phase Solutions, Co Ltd.

Email: nb_bolotina@mail.ru
瑞士, Lausanne, 1012

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