Defect structure of TiS 3  single crystals of the  A -ZrSe 3  type

N. B. Bolotina; I. G. Gorlova; I. A. Verin; A. N. Titov; A. V. Arakcheeva

doi:10.1134/S1063774516060055

Defect structure of TiS₃ single crystals of the A-ZrSe₃ type

Autores: Bolotina N.B.¹, Gorlova I.G.², Verin I.A.¹, Titov A.N.³, Arakcheeva A.V.⁴
Afiliações:
1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
2. Kotel’nikov Institute of Radioengineering and Electronics
3. Mikheev Institute of Metal Physics, Ural Branch
4. Phase Solutions, Co Ltd.
Edição: Volume 61, Nº 6 (2016)
Páginas: 923-930
Seção: Structure of Inorganic Compounds
URL: https://journals.rcsi.science/1063-7745/article/view/190371
DOI: https://doi.org/10.1134/S1063774516060055
ID: 190371

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The defect structure of TiS₃ single crystals of the A-ZrSe₃ type has been determined based on X-ray diffraction data. Shear defects manifest themselves as displacements of ab layers (which can imitate a twin) by ∼0.5a. Regular shears facilitate the formation of a superstructure along the c axis. A model of defect in the layer structure is proposed to explain the atomic displacements at an angle to the layer plane.