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Vol 41, No 4 (2019)

Production, Structure, Properties

Spark Plasma Sintering of Cu-(LaB6-TiB2) Metal-Ceramic Composite and Its Physical-Mechanical Properties

Soloviova T.O., Solodkyi I.V., Loboda P.I.

Abstract

A metal-ceramic composite Cu-(LaB6-TiB2) has been produced by the spark plasma sintering. The microstructure, phase composition, mechanical properties and resistivity of the composite are studied. An effective method for reinforcing the interface between the copper matrix and reinforced ceramic particles LaB6-TiB2 has been proposed and implemented. It is demonstrated that consolidation of the metal-ceramic composite by using LaB6-TiB2 particles with naked fibers almost doubles the material's strength. Furthermore, the use of reinforced ceramic particles provides the electrical conductivity on a level with the best materials for resistance-welding electrodes (88% IACS).

Journal of Superhard Materials. 2019;41(4):213-220
pages 213-220 views

Recovery of Adsorption Properties of Shungite

Diyuk V.E., Ishchenko O.V., Loginova O.B., Melnik L.M., Kisterska L.D., Garashchenko V.V., Lisovenko S.O., Beda O.A., Tkachuk N.A., Shevchenko O.Y., Turchun O.V.

Abstract

The condition of the surface of natural mesoporous carbonaceous material shungite has been investigated using the electron microscopy, X-ray phase and microspectrum analyses. The ability to recover the adsorption properties of shungite in respect to the extraction of higher alcohols and other impurities from water-alcohol solutions was investigated by the methods of thermogravimetry and IR spectroscopy. The main distinction of absorption spectra of used-up shungite with respect to the initial sample is the absence of absorption by hydroxyl groups (3380 cm−1) and significant reduction of the contribution of component at 1170 cm−1 that corresponds to absorption of phenol groups. It is shown that the heat treatment in argon, with water vapor and in the CO2 medium results in almost complete removal of sorbed organic substances and the regeneration of adsorption properties of shungite, the latest technique is more economically justified.

Journal of Superhard Materials. 2019;41(4):221-228
pages 221-228 views

Effect of Different Binder Phases on the Σ2 Grain Boundary Plane Distribution in Cemented Carbides

Yuan X.

Abstract

For WC-6 wt % Co and WC-6 wt % Ni composites, and by using five parameter analysis method as a new approach, the geometric and crystallographic features of carbide/carbide boundaries have been characterized. Two most frequently occurring WC/WC boundaries are 90° twist boundaries about [10–10] (Σ2 boundaries) and 27.8° twist boundaries about [0001] (Σ13a boundaries), the Σ2 boundary populations vary with binder phase types, and carbide crystals are most frequently terminated by (0001) and (10–10) surfaces, such preference does not significantly alter if Σ2 boundaries are partitioned.

Journal of Superhard Materials. 2019;41(4):229-236
pages 229-236 views

Effect of Graphite Addition on Impregnated Diamond Bit Properties

Xie L., Chen L., Huang X.

Abstract

Graphite was used as a solid lubricant to reduce thermal damage in diamond bit when drilling without coolant. Graphite was added to the bit matrix material to reduce friction coefficient and heat. The influence of content, granularity, and surface metallization of graphite on the mechanical property and dry friction properties of the matrix, as well as the effect of diamond lifetime in the working layer were studied. Results showed that the hardness, bending strength, and friction coefficient of matrix gradually decreased with the increase in graphite concentration. Meanwhile, the abrasion loss decreased first and then increased, and the lifetime of diamond in the working layer gradually increased. With the decrease in graphite granularity, the bending strength and friction coefficient of matrix gradually decreased, whereas the hardness, abrasion loss of matrix, and diamond lifetime in the working layer gradually increased. After surface metallization of graphite, the hardness, bending strength, friction coefficient, and abrasion loss of matrix increased, whereas the lifetime of diamond in the working layer decreased. This study lays a foundation for drilling without water.

Journal of Superhard Materials. 2019;41(4):237-246
pages 237-246 views

Investigation of Machining Processes

Machinability Investigation and Cost Estimation During Finish Dry Hard Turning of AISI 4340 Steel with Untreated and Cryo Treated Cermet Inserts

Das A., Patel S.K., Biswal B.B., Das S.R.

Abstract

For higher tool life of cutting inserts cryogenic treatment is considered as the most prominent method but no substantial researches have been found concerning the impact of cryogenic treatment on cermet inserts especially in hard turning. Therefore, in the present experimental investigation, the comparative assessment of various responses such as cutting force, flank wear, crater wear, chip morphology and surface roughness were carried out during machining of hardened steel with both untreated and cryo treated cermet inserts hard turning under dry cutting condition. Lastly, the input variables were optimized using Response surface methodology (RSM) to evaluate the tool life for the economic analysis. The experimental result demonstrated that the uncoated deep cryo treated with tempered cermet insert delivered better results in comparison to other cermet inserts. According to cost analysis, uncoated and deep cryo treated with tempered cermet insert was found to be the most economical among other cermet inserts at the optimum cutting condition.

Journal of Superhard Materials. 2019;41(4):247-264
pages 247-264 views

The Phonomenon of Material Side Flow During Finish Turning of EN X153CrMoV12 Hardened Steel with Tools Based on Polycrystalline Cubic Boron Nitride

Ociepa M., Jenek M., Feldshtein E., Leksycki K.

Abstract

The study presents the results of an analysis of the phenomenon of material side flow during finish turning of EN X153CrMoV12 (H12MF GOST 5950-2000) tool steel hardened to 63 ± 2 HRC with cutting tools made of polycrystalline composites based on polycrystalline cubic boron nitride. For an uncoated wedges of CBN 7025 the material side flow occurred for the entire range of tested cutting feed. For a CBN 8120 wedges with a TiA1N coating the side flow was observed exclusively for the cutting feed of f= 0.2 mm/rev. The researched phenomenon did not occur on the surfaces finished with a CBN 7015 tool coated with TiN.

Journal of Superhard Materials. 2019;41(4):265-271
pages 265-271 views

Specifying the Process Parameters for Diamond Dressing of Grinding Wheels

Shakhbazov Y.O., Shyrokov V.V., Fedorovych V.O.

Abstract

Theoretical and experimental investigations have provided a deep insight into the process of diamond dressing of vitrified grinding wheels under the mechanisms of micro- or macrofracture of abrasive grits. This permits determining the process parameters dressing in coarse and finish grinding operations. The authors propose equations for finding the depth of dressing for various types of have been proposed for different wheel working layer states.

Journal of Superhard Materials. 2019;41(4):272-277
pages 272-277 views

Letters to the Editor

The Influence of Circumferential Waviness of the Diamond Wheel Working Surface on the Machined Surface Roughness

Pasichnyi O.O., Lavrinenko V.I.

Abstract

The authors investigate the potential of damping down the undulating change of form of a diamond wheel working surface by dressing it with a single-point diamond tool. This is shown to alter the machined surface roughness parameters, namely: the height parameters decrease, the spacing of the profile irregularities and the parameters of the reference length of the profile grow.

Journal of Superhard Materials. 2019;41(4):278-280
pages 278-280 views

The Friction Coefficient of Natural Diamond Against Materials Based on Cubic Boron Nitride

Adamovskyi A.A., Kostenko A.D.

Abstract

It is demonstrated that in friction of a diamond pyramid against specimens of BN-based superhard materials the phase composition of the materials in contact has a dominant effect on the friction coefficient.

Journal of Superhard Materials. 2019;41(4):281-282
pages 281-282 views

Thermal Conductivity of Copper with the Addition of n- Layer Graphene

Shul’zhenko A.A., Sokolov A.N., Jaworska L., Gargin V.G., Kuz’menko E.F.

Abstract

The effect of the addition of n-layer graphene on the thermal conductivity of copper samples sintered at high pressure and temperature was studied. It was shown that the addition of graphene Gn (4) to copper powder in an amount of 0.2–0.4 wt % allows an increase in the value of thermal conductivity of samples by 14–37%.

Journal of Superhard Materials. 2019;41(4):283-285
pages 283-285 views