Simultaneous Determination of Copper(II) and Cobalt(II) Ions, Copper(II) and Manganese(II) Ions in Drinking Water Using Indicator Test Tubes Based on Carboxylic Cation-Exchangers
- 作者: Zharkova V.1, Bobkova L.1
-
隶属关系:
- Department of Chemistry, National Research Tomsk State University
- 期: 卷 74, 编号 7 (2019)
- 页面: 672-678
- 栏目: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/183245
- DOI: https://doi.org/10.1134/S1061934819050125
- ID: 183245
如何引用文章
详细
We investigated a possibility of determining two metal ions (Cu2+ and Co2+, Cu2+ and Mn2+) in a single water sample using an indicator test tube filled with a carboxylic cation exchanger of a macrocellular (KB-2E-10, KB-2E-16) or a macroporous (Tokem-250) structure. Under dynamic conditions, the separation of the chromatographic zones of colored Cu2+ and Co2+ ions was achieved in the presence of water macro components, that is, Ca2+ and Mg2+ ions. An analytical reagent, formaldoxime, was used to determine colorless Mn2+ ions. The performance characteristics of the developed procedures are determined. The lowest limit of detection for ions was obtained using a KB-2E-16 cation exchanger; it is 0.016 mg/L for Cu2+, 0.045 mg/L for Co2+, and 0.003 mg/L for Mn2+. The proposed procedures were used to analyze real samples for the concentration of Co2+ and Cu2+ or Mn2+ and Cu2+ on their simultaneous presence. The accuracy of the results was evaluated by the standard addition method.
作者简介
V. Zharkova
Department of Chemistry, National Research Tomsk State University
编辑信件的主要联系方式.
Email: petrovavalentina2012@mail.ru
俄罗斯联邦, Tomsk, 634050
L. Bobkova
Department of Chemistry, National Research Tomsk State University
Email: petrovavalentina2012@mail.ru
俄罗斯联邦, Tomsk, 634050