Отправить статью по E-mail Surface-enhanced Raman scattering sensing of trace fenthion coupled with stable silver colloids and OH stretching band of water as an internal standard
- Авторы: Teng Y.J.1, Liu W.H.1, Liu J.M.1, Nie Y.H.1, Li P.1, He C.J.1
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Учреждения:
- State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
- Выпуск: Том 71, № 9 (2016)
- Страницы: 891-895
- Раздел: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182039
- DOI: https://doi.org/10.1134/S106193481609015X
- ID: 182039
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Аннотация
The detection of trace fenthion using surface-enhanced Raman scattering (SERS) was proposed via the OH stretching band of water serving as an internal standard. The adsorption process of fenthion on the silver nanoparticle aggregates was characterized by UV-Visible absorption spectrometry and the optimal adsorption time was about 20 min. The OH stretching band of H2O molecule presented around 3100–3500 cm–1 in SERS spectrum was identified by density functional theory and it was not interfered with other characteristic peaks of fenthion. The linearity was obtained from the concentrations divided by the ratio of the benzene ring stretching area around 1073 cm–1 and the internal standard of OH stretching area from 3100 to 3500 cm–1, while the detection limit was calculated as 0.46 µM. The proposed SERS detection method was used in analyzing lake water sample with the recovery of 94–99%.
Об авторах
Y. Teng
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
Автор, ответственный за переписку.
Email: yuanjieteng@zjut.edu.cn
Китай, Zhejiang Province, 310014
W. Liu
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
Email: yuanjieteng@zjut.edu.cn
Китай, Zhejiang Province, 310014
J. Liu
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
Email: yuanjieteng@zjut.edu.cn
Китай, Zhejiang Province, 310014
Y. Nie
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
Email: yuanjieteng@zjut.edu.cn
Китай, Zhejiang Province, 310014
P. Li
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
Email: yuanjieteng@zjut.edu.cn
Китай, Zhejiang Province, 310014
C. He
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering
Email: yuanjieteng@zjut.edu.cn
Китай, Zhejiang Province, 310014
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