Surface-enhanced Raman scattering sensing of trace fenthion coupled with stable silver colloids and OH stretching band of water as an internal standard

Resumo

The detection of trace fenthion using surface-enhanced Raman scattering (SERS) was proposed via the OH stretching band of water serving as an internal standard. The adsorption process of fenthion on the silver nanoparticle aggregates was characterized by UV-Visible absorption spectrometry and the optimal adsorption time was about 20 min. The OH stretching band of H₂O molecule presented around 3100–3500 cm^–1 in SERS spectrum was identified by density functional theory and it was not interfered with other characteristic peaks of fenthion. The linearity was obtained from the concentrations divided by the ratio of the benzene ring stretching area around 1073 cm^–1 and the internal standard of OH stretching area from 3100 to 3500 cm^–1, while the detection limit was calculated as 0.46 µM. The proposed SERS detection method was used in analyzing lake water sample with the recovery of 94–99%.