Dissociative Electron Attachment to 2,6- and 2,5-Dihydroxyacetophenone


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Аннотация

Two model humic compounds, 2,6- and 2,5-dihydroxyacetophenone, were investigated by negative ion mass spectrometry. Dissociative electron attachment cross-sections and negative ion autodetachment lifetimes were measured in the electron energy region 0–10 eV. Adiabatic electron affinities of the compounds under investigation were evaluated. The results obtained were rationalized using DFT B3LYP/6-31G+(d) quantum-chemical calculations.

Авторлар туралы

N. Asfandiarov

Institute of Molecular and Crystal Physics, Ufa Federal Research Centre, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: nail@anrb.ru
Ресей, Ufa, 450075

S. Pshenichnyuk

Institute of Molecular and Crystal Physics, Ufa Federal Research Centre, Russian Academy of Sciences

Email: nail@anrb.ru
Ресей, Ufa, 450075

E. Nafikova

Institute of Molecular and Crystal Physics, Ufa Federal Research Centre, Russian Academy of Sciences

Email: nail@anrb.ru
Ресей, Ufa, 450075

R. Rakhmeyev

Institute of Molecular and Crystal Physics, Ufa Federal Research Centre, Russian Academy of Sciences

Email: nail@anrb.ru
Ресей, Ufa, 450075

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