Catalytic spectrophotometric determination of trace amount of cerium(IV)
- Autores: Zhai Q.1, Hu W.1, Chai Z.1
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Afiliações:
- Research Center for Nanotechnology, South Campus
- Edição: Volume 72, Nº 10 (2017)
- Páginas: 1024-1027
- Seção: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182636
- DOI: https://doi.org/10.1134/S1061934817100148
- ID: 182636
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Resumo
Based on a property that in dilute hydrochloric acid hydrogen peroxide oxidizes Ponceau S to fade and cerium(IV) has a catalytic effect on the reaction, a new spectrophotometric method was developed for the determination of trace cerium(IV). At 450 nm, the cerium(IV) concentration presents a good linear relationship over the range of 0.08‒4 μg/mL with the fading degree ΔA. Its linear regression equation is ΔA = 0.0475c (μg/mL) + 0.0007, with a correlation coefficient of 0.9991. The detection limit of method is 0.05 μg/mL. The method has been successfully applied to the determination of cerium in water and molecular sieve samples with good results. The relative standard deviations of eleven determinations were 0.97‒1.11 and 0.19‒1.01%, respectively. The recoveries of standard additions were 99.4‒99.9 and 99.2‒101.0%, respectively. The reliability of this method was certified by parallel determination against the dibromo-p-chlorochlorophosphonazo spectrophotometry.
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Sobre autores
Qing-Zhou Zhai
Research Center for Nanotechnology, South Campus
Autor responsável pela correspondência
Email: zhaiqingzhou@163.com
República Popular da China, 7186 Weixing Road, Changchun, 130022
Wei-Hua Hu
Research Center for Nanotechnology, South Campus
Email: zhaiqingzhou@163.com
República Popular da China, 7186 Weixing Road, Changchun, 130022
Zhong Chai
Research Center for Nanotechnology, South Campus
Email: zhaiqingzhou@163.com
República Popular da China, 7186 Weixing Road, Changchun, 130022
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