Study of the Aquatic Chlorination of UV Filter Avobenzone in the Presence of Inorganic Salts by Gas Chromatography–High-Resolution Mass Spectrometry
- Autores: Detenchuk E.A.1, Chen J.1, Polyakova O.V.1, Trebse P.2, Pokryshkin S.A.3, Lebedev A.T.1,3
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Afiliações:
- Department of Chemistry, Moscow State University
- Faculty of Health Sciences, University of Ljubljana
- Core Facility Center “Arktika,” Northern (Arctic) Federal University
- Edição: Volume 74, Nº 13 (2019)
- Páginas: 1271-1276
- Seção: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/183361
- DOI: https://doi.org/10.1134/S1061934819130069
- ID: 183361
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Resumo
Disinfection is an essential technological stage in water treatment. It is used not only for potable water but also for, e. g., swimming pool water. Water chlorination is the most common method for eliminating microorganisms today. However, active chlorine reacting with natural and anthropogenic compounds dissolved in water gives rise to the formation of numerous compounds that may be hazardous to human health. The assortment of anthropogenic contaminants grows every year; UV filters are well represented among them. Since recently, they are referred to as ecotoxicants, while their application to skin protection becomes more and more popular all over the world. Over 30 compounds, including numerous halogenated derivatives forming in the aquatic chlorination of a popular UV filter avobenzone in the presence of inorganic salts of iron and copper, as well as bromides and iodides, were identified by gas-chromatography–high-resolution mass spectrometry. The study demonstrated the notable variation of the qualitative and quantitative composition of the reaction products depending on the added salt. It is worth mentioning the formation of brominated and iodinated products.
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Sobre autores
E. Detenchuk
Department of Chemistry, Moscow State University
Autor responsável pela correspondência
Email: mocehops@ya.ru
Rússia, Moscow, 119991
J. Chen
Department of Chemistry, Moscow State University
Email: mocehops@ya.ru
Rússia, Moscow, 119991
O. Polyakova
Department of Chemistry, Moscow State University
Email: mocehops@ya.ru
Rússia, Moscow, 119991
P. Trebse
Faculty of Health Sciences, University of Ljubljana
Email: mocehops@ya.ru
Eslovênia, Ljubljana, 1000
S. Pokryshkin
Core Facility Center “Arktika,” Northern (Arctic) Federal University
Email: mocehops@ya.ru
Rússia, Arkhangelsk, 163002
A. Lebedev
Department of Chemistry, Moscow State University; Core Facility Center “Arktika,” Northern (Arctic) Federal University
Email: mocehops@ya.ru
Rússia, Moscow, 119991; Arkhangelsk, 163002
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