Chromatographic Analytical Control and Purification of Water-Soluble Carboxylated Copolymers Based on N-Vinylamides


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Abstract

Chromatographic methods of analysis of the products of the radical copolymerization of random copolymers of N-vinyl-2-pyrrolidone and 6-crotonoyl aminohexanoic acid are developed and molecular characteristics of the copolymers are determined. A method is proposed for the purification of the obtained carboxylated water-soluble copolymers of monomeric hydrophobic acid impurities by low-pressure gel-permeation chromatography.

About the authors

V. D. Krasikov

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Author for correspondence.
Email: krasikov@lenchrom.ru
Russian Federation, St. Petersburg, 199004

M. S. Borisenko

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Email: krasikov@lenchrom.ru
Russian Federation, St. Petersburg, 199004

I. I. Malakhova

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Email: krasikov@lenchrom.ru
Russian Federation, St. Petersburg, 199004

N. I. Gorshkov

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Email: krasikov@lenchrom.ru
Russian Federation, St. Petersburg, 199004

M. A. Bezrukova

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Email: krasikov@lenchrom.ru
Russian Federation, St. Petersburg, 199004

M. V. Solovskii

Institute of Macromolecular Compounds of the Russian Academy of Sciences

Email: krasikov@lenchrom.ru
Russian Federation, St. Petersburg, 199004


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