Rapid Control of the Octane Number of Gasolines Using an IR Octanometer


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The problem of using octanometers for the rapid control of the octane number of compounds in the production of commercial gasoline is considered, and the factors forming it are indicated. Error spectra of a multidimensional absorption spectral analytic signal of commercial gasolines and compounds of their individual fractions (components) were studied in measurements in the mid-IR region. The effect of a change of the proportion of the main constituents (aromatic hydrocarbons, benzene catalysate, isomerizate, methyl tert-butyl ether, and isopentane) in the compound on the spectra of commercial gasolines was evaluated. Multidimensional measurements of light absorption by gasolines in a wide spectral region and difference spectra were used. It was shown that spectral noise does not form limitations in spectroscopic measurements, while uncontrollable variations in the process conditions can form significant deviations in the absorption spectra, leading to problems in using calibration characteristics based on commercial gasoline samples.

About the authors

V. N. Bocharov

Department of Physics, St. Petersburg State University

Email: nemec_vm@mail.ru
Russian Federation, St. Petersburg, 198504

A. A. Ganeev

Department of Chemistry, St. Petersburg State University

Email: nemec_vm@mail.ru
Russian Federation, St. Petersburg, 198504

I. O. Konyushenko

Department of Physics, St. Petersburg State University

Email: nemec_vm@mail.ru
Russian Federation, St. Petersburg, 198504

V. M. Nemets

Department of Physics, St. Petersburg State University

Author for correspondence.
Email: nemec_vm@mail.ru
Russian Federation, St. Petersburg, 198504

S. A. Peganov

Department of Physics, St. Petersburg State University

Email: nemec_vm@mail.ru
Russian Federation, St. Petersburg, 198504


Copyright (c) 2019 Pleiades Publishing, Inc.

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies