New Directions in Using Ionic Liquids in Analytical Chemistry. 1: Liquid–Liquid Extraction


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Abstract

The first part of the review presents general information and brief historical notes about ionic liquids (ILs) along with various versions of microextraction preconcentration using ILs: single-drop extraction, membrane extraction, dispersive liquid–liquid microextraction, in situ ionic liquid-based dispersive microextraction, etc. A review of papers on the extraction of metal ions and organic compounds in ILs for chemical analysis is presented. Aqueous biphasic systems based on ILs immiscible with water and salting-out agents are described; examples of such systems, their advantages, and factors affecting phase separation are considered.

About the authors

I. V. Pletnev

Department of Chemistry, Moscow State University

Author for correspondence.
Email: pletnev@analyt.chem.msu.ru
Russian Federation, Moscow, 119991

S. V. Smirnova

Department of Chemistry, Moscow State University

Email: pletnev@analyt.chem.msu.ru
Russian Federation, Moscow, 119991

N. V. Shvedene

Department of Chemistry, Moscow State University

Email: pletnev@analyt.chem.msu.ru
Russian Federation, Moscow, 119991


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