Sorption–Mass Spectrometry Determination of Platinum Metals in Basic Rocs and Ores
- Authors: Dubenskiy A.S.1,2, Bol’shov M.A.1,3, Seregina I.F.1
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Affiliations:
- Department of Chemistry, Moscow State University
- Geological Institute, Russian Academy of Sciences
- Institute of Spectroscopy, Russian Academy of Sciences
- Issue: Vol 74, No 1 (2019)
- Pages: 33-40
- Section: Reviews
- URL: https://journals.rcsi.science/1061-9348/article/view/183122
- DOI: https://doi.org/10.1134/S1061934819010064
- ID: 183122
Cite item
Abstract
The results of a systematic study of sorption systems for the reversible group extraction of Ru, Rh, Pd, Ir, and Pt and their subsequent determination by inductively coupled plasma mass spectrometry are presented. The sorption system includes an sorbent, a reagent, and a desorbing solution. Purolite MN-200, НP, and Styrosorb hypercrosslinked polystyrene sorbents and Strata sorbents with immobilized nitrogen atoms were studied. Various aliphatic and aromatic amines were used as ion-pair amine reagents for the sorption extraction of PGMs. A possibility of the desorption of Ru, Rh, Pd, Ir, and Pt complexes with reagents of different nature was studied. Sorption systems were selected for the preconcentration of PGMs from solutions obtained after the decomposition of rocks. A flow-injection method for introducing high-salt and organic solutions into a mass spectrometer was proposed. Possible spectral and nonspectral effects were investigated, and the conditions for quantifying Ru, Rh, Pd, Ir, and Pt in the obtained preconcentrates were selected.
About the authors
A. S. Dubenskiy
Department of Chemistry, Moscow State University; Geological Institute, Russian Academy of Sciences
Email: sereginairinaf@mail.ru
Russian Federation, Moscow, 119991; Moscow, 119017
M. A. Bol’shov
Department of Chemistry, Moscow State University; Institute of Spectroscopy, Russian Academy of Sciences
Email: sereginairinaf@mail.ru
Russian Federation, Moscow, 119991; Moscow, Troitsk, 142190
I. F. Seregina
Department of Chemistry, Moscow State University
Author for correspondence.
Email: sereginairinaf@mail.ru
Russian Federation, Moscow, 119991