Subcritical water: Use in chemical analysis
- Authors: Borisova D.R.1, Statkus M.A.1, Tsizin G.I.1, Zolotov Y.A.1
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Affiliations:
- Department of Chemistry
- Issue: Vol 72, No 8 (2017)
- Pages: 823-836
- Section: Reviews
- URL: https://journals.rcsi.science/1061-9348/article/view/182583
- DOI: https://doi.org/10.1134/S1061934817080044
- ID: 182583
Cite item
Abstract
The review shows prospects of the use of subcritical water instead of organic solvents and aqueous–organic mixtures at different stages of analysis. Subcritical water was applied to the extraction of target compounds from natural samples, such as soils, sand, and plant raw materials. The use of subcritical water expands possibilities of HPLC. The use of subcritical water as an eluent in HPLC is complicated by the possible destruction of the adsorbent and the decomposition of substances to be determined at elevated temperatures. Adsorbents based on zirconium and titanium oxides, some polymeric adsorbents, and porous graphitized carbon are stable in the medium of subcritical water. Subcritical water can be used at several stages of analysis, for example, for the extraction and subsequent chromatographic separation of analytes.
About the authors
D. R. Borisova
Department of Chemistry
Email: tsisin@analyt.chem.msu.ru
Russian Federation, Moscow, 119992
M. A. Statkus
Department of Chemistry
Email: tsisin@analyt.chem.msu.ru
Russian Federation, Moscow, 119992
G. I. Tsizin
Department of Chemistry
Author for correspondence.
Email: tsisin@analyt.chem.msu.ru
Russian Federation, Moscow, 119992
Yu. A. Zolotov
Department of Chemistry
Email: tsisin@analyt.chem.msu.ru
Russian Federation, Moscow, 119992