On Enhancement of the Adsorption-Layer Effect at the Metallic Electrode−Liquid Electrolyte Interface in Specular Neutron Reflectometry Experiments


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The possibilities for optimizing the substrate/electrode/electrolyte structure are considered in order to obtain the maximum change in the specular-reflection curves obtained in neutron reflectometry experiments at the electrochemical interfaces between a metallic electrode and liquid electrolyte containing Li+ ions during their operation. The characteristic relations between the scattering length densities of the components, for which the reflection curves most fully provide information about the structure of the solid electrolyte interphase layer formed on the electrode surface during the charge–discharge processes, are determined and analyzed.

作者简介

V. Petrenko

Frank Laboratory of Neutron Physics; Taras Shevchenko Kyiv National University

编辑信件的主要联系方式.
Email: vip@nf.jinr.ru
俄罗斯联邦, Dubna, Moscow oblast, 141980; Kyiv, 01033

Ye. Kosiachkin

Frank Laboratory of Neutron Physics; Taras Shevchenko Kyiv National University

Email: vip@nf.jinr.ru
俄罗斯联邦, Dubna, Moscow oblast, 141980; Kyiv, 01033

L. Bulavin

Taras Shevchenko Kyiv National University

Email: vip@nf.jinr.ru
乌克兰, Kyiv, 01033

M. Avdeev

Frank Laboratory of Neutron Physics; State University “Dubna”

Email: vip@nf.jinr.ru
俄罗斯联邦, Dubna, Moscow oblast, 141980; Dubna, Moscow oblast, 141982

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