New oxyfluoroniobate glasses in CdNbOF5–BaF2–ErF3 systems
- Authors: Ignatieva L.N.1, Marchenko Y.V.1, Savchenko N.N.1, Mashchenko V.A.1, Mirochnik A.G.1
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Affiliations:
- Institute of Chemistry, FEB RAS
- Issue: No 4 (2025)
- Pages: 67-77
- Section: Advanced materials
- URL: https://journals.rcsi.science/0869-7698/article/view/351725
- DOI: https://doi.org/10.7868/S3034530825040069
- ID: 351725
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Abstract
New glasses have been synthesized in the CdNbOF5–BaF2–хErF3(х = 0−5.0 mol. %) system. The glasses are two-phase. The ratio of amorphous phases, depending on the erbium trifluoride content in the glass, affects the thermal, crystallization, structural and optical characteristics of the glasses. When the ErF3content in the glass is 3 mol. %, rearrangements in the glass structure occur, leading to an increase in the connectivity of oxyfluoroniobate networks. Glasses in the CdNbOF5–BaF2–ErF3system are characterized by green luminescence of Er3+, corresponding to the transitions:4S3/2→4I15/2(544 nm),2Н11/2→4I15/2(551 nm). The luminescence intensity increases with an increase in the ErF3content to 2 mol. %. A further increase in the content of erbium trifluoride in the glass composition leads to a gradual decrease in the luminescence intensity, caused by concentration quenching and changes in the structure and phase composition at given dopant concentrations.
Keywords
About the authors
L. N. Ignatieva
Institute of Chemistry, FEB RAS
Email: ignatieva@ich.dvo.ru
Vladivostok, Russia
Y. V. Marchenko
Institute of Chemistry, FEB RAS
Email: gor_dvo@mail.ru
Vladivostok, Russia
N. N. Savchenko
Institute of Chemistry, FEB RAS
Email: savchenko@ich.dvo.ru
Vladivostok, Russia
V. A. Mashchenko
Institute of Chemistry, FEB RAS
Email: mashchenko@ich.dvo.ru
Vladivostok, Russia
A. G. Mirochnik
Institute of Chemistry, FEB RAS
Email: mirochnik@ich.dvo.ru
Vladivostok, Russia
References
- Mateski M., Poulain Mi., Poulain Ma. Verres aux halogenures de cadmium 1. Verres fluores. Mat. Res. Bull.1982;17:1275–1281.
- Ishwar D. Aggarwal, Grant Lu. Fluoride glass fiber optics. New York: Acad. Press; 1991. 416 p.
- DoweidarH.,El-EgiliK.,RamadaR.M.,KhalilE.Structural studies and properties of CdF2–B2O3glasses.J. Non-Cryst. Solids.2018;481:494–502. https://doi.org/10.1016/j.jnoncrysol.2017.11.036
- Klouche Bouchaour Z.C., Polain M., Belhadji M., Hager I., Mallawany R.E.I. New oxyfluoroniobate glasses.J. Non-Cryst. Solids.2005;351:816. https://doi.org/10.1016/j.jnoncrysol.2005.01.081
- Polishchuk S.A., Ignat’eva L.N., Marchenko Yu.V., Bouznik V.M.Glass Phys. Chem.2011;37(1):1–20. https://doi.org/10.1134/S108765961101010X
- Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Sarin S.A. Synthesis, structure and crystallization of glasses in the CdNbOF5–BaF2–InF3system.Ceram. Int.2019;45:17737–17741. https://doi.org/10.1016/j.ceramint.2019.05.343
- Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Mashchenko V.A., Sarin S.А. New glassea in the systems of MNbOF5–BaF2–InF3(M−Mn, Cd, Zn). Vestnik of the FEB RAS.2024;(6):187–202. (In Russ.).
- Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Mashchenko V.A., Mirochnik A.G., Galkin K.N. New Glasses in the ZnNbOF5–BaF2–InF3system.J. Non-Cryst. Solids.2024;623. 1226919. https://doi.org/10.1016/j.jnoncrysol.2023.122691
- Ignatieva L.N., Savchenko N.N., Marchenko Y.V., Mashchenko V.A., Bouznik V.M. Raman study of glasses in the NbO2F–BaF2–InF3–ErF3and CdNbOF5–BaF2–InF3systems,Nanosystems: Phys. Chem. Math.2020;11(3):0–4. https://doi.org/10.17586/2220-8054-2020-11-3-333-337
- Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Mashchenko V.A., Mirochnik A.G., Galkin K.N. New Glasses in the ZnNbOF5–BaF2–ErF3system. Indian J. Phys.2025;1. https://doi.org/10.1007/s12648-024-03531-7
- Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Mashchenko V.A., Mirochnik A.G., Pikalov D.O. Glasses in the MnNbOF5–BaF2–ErF3system.J. Non-Cryst. Solids.2025. (In print).
- Zhang X., Gong M. A new red-emitting Ce3+, Mn2+-doped barium lithium silicate phosphor for NUV LED application.Mater. Lett.2011;65(10):1756–1758. https://doi.org/10.1016/j.matlet.2011.03.075
- Aseev V., Kolobkova E., Nekrasova Ya., Nikonorov N., Rokhmin A. Manganese luminescence in fluorine-phosphate glasses.Sci. Tech. J. Inf. Technol. Mech. Opt.2012;82(6):36–39.
- Davidovich R.L., Levchishina T.F., Kaidalova T.A., Sergienko V.I. The synthesis and properties of oxofluoroniobates and fluorotantalates of bivalent metals.J. Less Com. Metals. 1972;27(1):35.
- Ignat’eva L.N., Savchenko N.N., Marchenko Yu.V., Zverev G.A., Buznik V.M. Structure and Crystallization of Glasses in the MnNbOF5–BaF2–InF3System.Rus. J. Inorg. Chem.2018;63(11):1389–1394. https://doi.org/10.1134/S0036023618110062
- Ignatieva L.N., Surovtsev N.V., Savchenko N.N., Adichtchev S.V., Polyshchuk S.A., Marchenko Yu.V., Bouznik V.M. Glasses in the system of MnNbOF5–BaF2–BiF3–ErF3.J. Non-Cryst. Solids.2011;357:3807–3812. https://doi.org/10.1016/j.jnoncrysol.2011.08
- Ignatieva L.N. Structure and Formation Principles of Fluoride Glasses from the Data of Quantum Chemistry and Vibration Spectroscopy: the doctoral thesis. Vladivostok; 2000. 270 p. (In Russ.).
- Zolin V.F., Koreneva L.G. Rare earth probe in chemistry and biology.Moscow: Nauka; 1980. 350 p. (In Russ.).
- Lakowicz J.R. Principles of Fluorescence Spectroscopy. Maryland, MD 21201 USA: University of Maryland School of Medicine Baltimore;1983.
- Blasse G., GrabmaierB.C. Luminescent Materials. New York: Springer; 1994. 234 p. https://doi.org/10.1007/978-3-642-79017-1
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