Synthesis and Study of Catalytic Properties of Rh-Containing Structured Catalyst for Diesel Fuel Conversion into Synthesis Gas

V. A. Shilov; Шилов В. А.; V. N. Rogozhnikov; Рогожников В. Н.; D. I. Potemkin; Потемкин Д. И.; P. V. Snytnikov; Снытников П. В.

doi:10.31857/S0453881123010070

Synthesis and Study of Catalytic Properties of Rh-Containing Structured Catalyst for Diesel Fuel Conversion into Synthesis Gas

Authors: Shilov V.A.¹^,2, Rogozhnikov V.N.¹, Potemkin D.I.¹^,2, Snytnikov P.V.¹
Affiliations:
1. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Science
2. Novosibisk State University
Issue: Vol 64, No 1 (2023)
Pages: 109-118
Section: Articles
URL: https://journals.rcsi.science/0453-8811/article/view/137035
DOI: https://doi.org/10.31857/S0453881123010070
EDN: https://elibrary.ru/KIURFI
ID: 137035

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Abstract

In this work, we improved the technique for depositing the active oxide Ce_0.75Zr_0.25O_{2 – δ} on a structured FeCrAl alloy substrate. The essence of the method is the coprecipitation of cerium and zirconium oxides on a FeCrAl grid from an aqueous solution of their nitrates Ce(NO₃)₃·6H₂O and ZrO₂(NO₃)₂·7–8H₂O during homogeneous hydrolysis with ammonia. It was shown by XRD analysis that in the sample obtained by co-precipitation, more cerium-zirconium oxide phase is formed, moreover, it is more dispersed than obtained by impregnation technique. This method contributes to the formation of a coating with a larger specific surface area. The developed catalyst has a high activity under the conditions of autothermal reforming of diesel fuel. In the course of life tests for 200 h, it was found that the carbonization of the catalyst at a rate of 8.6 mg_c\({\text{g}}_{{{\text{cat}}}}^{{ - 1}}\) h^–1, as well as the accumulation of sulfur, did not affect the productivity of the catalyst with respect to synthesis gas, which was ~ 8 m³ \({\text{L}}_{{{\text{cat}}}}^{{ - 1}}\) h^–1.

Keywords

diesel fuel, structured catalyst, autothermal reforming, synthesis gas, fuel cell, hydrogen

References

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