Synthesis and Study of Catalytic Properties of Rh-Containing Structured Catalyst for Diesel Fuel Conversion into Synthesis Gas

V. A. Shilov; Шилов В. А.; V. N. Rogozhnikov; Рогожников В. Н.; D. I. Potemkin; Потемкин Д. И.; P. V. Snytnikov; Снытников П. В.

doi:10.31857/S0453881123010070

Synthesis and Study of Catalytic Properties of Rh-Containing Structured Catalyst for Diesel Fuel Conversion into Synthesis Gas

作者: Shilov V.¹^,2, Rogozhnikov V.¹, Potemkin D.¹^,2, Snytnikov P.¹
隶属关系:
1. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Science
2. Novosibisk State University
期: 卷 64, 编号 1 (2023)
页面: 109-118
栏目: Articles
URL: https://journals.rcsi.science/0453-8811/article/view/137035
DOI: https://doi.org/10.31857/S0453881123010070
EDN: https://elibrary.ru/KIURFI
ID: 137035

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
作者简介
参考
补充文件
统计

详细

In this work, we improved the technique for depositing the active oxide Ce_0.75Zr_0.25O_{2 – δ} on a structured FeCrAl alloy substrate. The essence of the method is the coprecipitation of cerium and zirconium oxides on a FeCrAl grid from an aqueous solution of their nitrates Ce(NO₃)₃·6H₂O and ZrO₂(NO₃)₂·7–8H₂O during homogeneous hydrolysis with ammonia. It was shown by XRD analysis that in the sample obtained by co-precipitation, more cerium-zirconium oxide phase is formed, moreover, it is more dispersed than obtained by impregnation technique. This method contributes to the formation of a coating with a larger specific surface area. The developed catalyst has a high activity under the conditions of autothermal reforming of diesel fuel. In the course of life tests for 200 h, it was found that the carbonization of the catalyst at a rate of 8.6 mg_c\({\text{g}}_{{{\text{cat}}}}^{{ - 1}}\) h^–1, as well as the accumulation of sulfur, did not affect the productivity of the catalyst with respect to synthesis gas, which was ~ 8 m³ \({\text{L}}_{{{\text{cat}}}}^{{ - 1}}\) h^–1.

关键词

diesel fuel, structured catalyst, autothermal reforming, synthesis gas, fuel cell, hydrogen

参考

Бадмаев С.Д., Беляев В.Д., Собянин В.А. // Кинетика и катализ. 2022. Т. 63. № 3. С. 394.
Горлова А.М., Симонов П.А., Стонкус О.А., Пахарукова В.П., Снытников П.В., Потемкин Д.И. // Кинетика и катализ. 2021. Т. 62. № 6. С. 773.
Юсенко М.В., Беляев В.Д., Демин А.К., Бронин Д.И., Саланов А.Н., Собянин В.А., Снытников П.В., Потемкин Д.И. // Кинетика и катализ. 2022. Т. 63. № 1. С. 138.
Shigarov A.B., Kireenkov V.V., Kuzmin V.A., Kuzin N.A., Kirillov V.A. // Catal. Today. 2009. V. 144. № 3–4. P. 341.
Alvarez-Galvan M.C., Navarro R.M., Rosa F., Briceño Y., Gordillo Alvarez F., Fierro JL.G. // Int. J. Hydrogen Energy. 2008. V. 33. № 2. P. 652–663.
Bae J., Lee S., Kim S., Oh J., Choi S., Bae M., Kang I., Katikaneni S.P. // Int. J. Hydrogen Energy. 2016. V. 41. № 44. P. 19990.
Bae M., Cheon H., Oh J., Kim D., Bae J., Katikaneni S.P. // Int. J. Hydrogen Energy. 2021. V. 46. № 52. P. 26575.
Ju D.G., Jo S.B., Ha D.S., Kim T.Y., Jung S.Y., Chae H.J., Lee S.C., Kim J.C. // Catalysts. 2019. V. 9. № 7. P. 573.
Karatzas X., Jansson K., Dawody J., Lanza R., Pettersson L.J. // Appl. Catal. B: Env. 2011. V. 101. № 3–4. P. 226.
Karatzas X., Dawody J., Grant A., Svensson E.E., Pettersson L.J. // Catal. Today. 2011. P. 515.
Kim D., Choi S., Jeong S., Bae M., Katikaneni S.P., Bae J., Heo S., Lee J.H. // Chem. Eng. J. 2021. V. 424. P. 130 564.
Pasel J., Samsun R.C., Meißner J., Tschauder A., Peters R. // Int. J. Hydrogen Energy. 2019. V. 11. P. 137.
Rogozhnikov V.N., Kuzin N.A., Snytnikov P.V., Potemkin D.I., Shoynkhorova, T.B., Simonov P.A., Shilov V.A., Ruban N.V., Kulikov A.V., Sobyanin V.A. // Chem. Eng. J. 2019. V. 374. P. 511.
Rogozhnikov V.N., Potemkin D.I., Ruban, N.V., Shilov V.A., Salanov A.N., Kulikov A.V., Simonov P.A., Gerasimov E.Y., Sobyanin V.A., Snytnikov P.V. // Mater. Lett. 2019. V. 257. P. 126715.
Samsun R.C., Prawitz M., Tschauder A., Meißner J., Pasel J., Peters R. // Appl. Energy. 2020. V. 279. P. 115882.
Shekhawat D., Gardner T.H., Berry D.A., Salazar M., Haynes D.J., Spivey J.J. // Appl. Catal. A: Gen. 2006. V. 311. № 1–2. P. 8.
Shilov V.A., Rogozhnikov V.N., Zazhigalov S.V., Potemkin D.I., Belyaev V.D., Shashkov M.V., Zagoruiko A.N., Sobyanin V.A., Snytnikov P.V. // Int. J. Hydrogen Energy. 2021. V. 46. № 72. P. 35866.
Shilov V.A., Rogozhnikov V.N., Ruban N.V., Potemkin D.I., Simonov P.A., Shashkov M.V., Sobyanin V.A., Snytnikov P.V. // Catal. Today. 2021. V. 379. P. 42.
Shilov V.A., Rogozhnikov V.N., Potemkin D.I., Belyaev V.D., Shashkov M.V., Sobyanin V.A., Snytnikov P.V. // Int. J. Hydrogen Energy. 2022. V. 47. № 21. P. 11316.
Younis M.N., Malaibari Z.O., Ahmad W., Ahmed S. // Energy and Fuels. 2018. V. 32. № 6. P. 7054.
Zazhigalov S.V., Rogozhnikov V.N., Snytnikov P.V., Potemkin D.I., Simonov P.A., Shilov V.A., Ruban N.V., Kulikov A.V., Zagoruiko A.N., Sobyanin V.A. // Chem. Eng. Process. Process Intensif. 2020. V. 150. P. 107876.
Zazhigalov S.V., Shilov V.A., Rogozhnikov V.N., Potemkin D.I., Sobyanin V.A., Zagoruiko A.N., Snytnikov P.V. // Catal. Today. 2021. V. 378. P. 240.
Zazhigalov S.V., Shilov V.A., Rogozhnikov V.N., Potemkin D.I., Sobyanin V.A., Zagoruiko A.N., Snytnikov P.V. // Chem. Eng. J. 2022. V. 442. P. 136160.
Симонов П.А., Шойнхорова Т.Б., Снытников П.В., Потемкин Д.И., Беляев В.Д. Патент RU 2653360 C1, 2017.
Porsin A.V., Kulikov A.V., Rogozhnikov V.N., Serkova A.N., Salanov A.N., Shefer K.I. // Catal. Today. 2016. V. 273. P. 213.
Rogozhnikov V.N., Potemkin D.I., Pakharukova V.P., Belyaev V.D., Nedolivko V.V., Glotov A.P., Sobyanin V.A., Snytnikov P.V. // Int. J. Hydrogen Energy. 2021. V. 46. № 72. P. 35853.
Shoynkhorova T.B., Simonov P.A., Potemkin D.I., Snytnikov P.V., Belyaev V.D., Ishchenko A.V., Svintsitskiy D.A., Sobyanin V.A. // Appl. Catal. B: Env. 2018. V. 237. P. 237. 1.