Универсальная электрокаталитическая система для превращения спиртов в карбонильные соединения и функциональные производные карбоновых кислот
- Авторы: Кашпарова В.П.1, Шубина Е.Н.1,2, Токарев Д.В.1, Антропов Г.П.2, Жукова И.Ю.2
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Учреждения:
- Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова
- Донской государственный технический университет
- Выпуск: Том 59, № 10 (2023)
- Страницы: 579-592
- Раздел: Статьи
- URL: https://journals.rcsi.science/0424-8570/article/view/141822
- DOI: https://doi.org/10.31857/S0424857023100079
- EDN: https://elibrary.ru/YIZUEZ
- ID: 141822
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Аннотация
Разработана универсальная каталитическая система 4-ацетамидо-2,2,6,6-тетраметилпиперидин-1-оксил/KI/пиридиновое основание для непрямого электроокисления спиртов в карбонильные соединения и производные карбоновых кислот. Использование пиридина, 2,6-лутидина или коллидина позволило получить карбонильные соединения (выход до 100%) после пропускания 2–2.2 F. В присутствии пиридина спирты жирного и жирно-ароматического рядов превращены в симметричные сложные эфиры (выход до 35%) после пропускания 4 F. Ангидриды кислот (выход до 80%) образуются при использовании 2,6-лутидина или коллидина после пропускания 5–6 F. В присутствии 2,6-лутидина и источника азота получены нитрилы (выход до 99%) после пропускания 4–4.5 F.
Ключевые слова
Об авторах
В. П. Кашпарова
Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова
Email: kashparova2013@mail.ru
Россия, 346428, Новочеркасск, ул. Просвещения, 132
Е. Н. Шубина
Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова; Донской государственный технический университет
Email: iyuzh@mail.ru
Россия, 346428, Новочеркасск, ул. Просвещения, 132; Россия, 344000, Ростов-на-Дону, пл. Гагарина, 1
Д. В. Токарев
Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова
Email: iyuzh@mail.ru
Россия, 346428, Новочеркасск, ул. Просвещения, 132
Г. П. Антропов
Донской государственный технический университет
Email: iyuzh@mail.ru
Россия, 344000, Ростов-на-Дону, пл. Гагарина, 1
И. Ю. Жукова
Донской государственный технический университет
Автор, ответственный за переписку.
Email: iyuzh@mail.ru
Россия, 344000, Ростов-на-Дону, пл. Гагарина, 1
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