UNIVERSAL ELECTROCATALYTIC SYSTEM FOR CONVERSION OF ALCOHOLS INTO CARBONYL COMPOUNDS AND CARBOXY ACID FUNCTIONAL DERIVATIVES

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Abstract

A universal catalytic system 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl/KI/pyridine base for the conversion of alcohols into carbonyl compounds and derivatives of carboxylic acids has been developed. The use of pyridine, 2,6-lutidine or collidine made it possible to obtain carbonyl compounds (yield up to 100%) after 2-2.2 F/mol. In the presence of pyridine, aliphatic alcohols are converted to esters (yield up to 35%) after 3-4 F/mol. Acid anhydrides (yield up to 80%) are formed using 2,6-lutidine or collidine after 5-6 F/mol. Nitriles were obtained in the presence of 2,6-lutidine and a source of nitrogen (yield up to 99%) after 3-4 F/mol.

About the authors

V. P. Kashparova

Platov South-Russian State Polytechnic University (NPI)

Email: kashparova2013@mail.ru
Russia, 346428, Novocherkassk, st. Prosveshcheniya, 132

E. N. Shubina

Platov South-Russian State Polytechnic University (NPI); Don State Technical University

Email: iyuzh@mail.ru
Russia, 346428, Novocherkassk,st. Prosveshcheniya, 132; Russia, 344000, Rostov-on-Don, sq. Gagarina, 1

D. V. Tokarev

Platov South-Russian State Polytechnic University (NPI)

Email: iyuzh@mail.ru
Russia, 346428, Novocherkassk, st. Prosveshcheniya, 132

G. P. Antropov

Don State Technical University

Email: iyuzh@mail.ru
Russia, 344000, Rostov-on-Don, sq. Gagarina, 1

I, Yu. Zhukova

Don State Technical University

Author for correspondence.
Email: iyuzh@mail.ru
Russia, 344000, Rostov-on-Don, sq. Gagarina, 1

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