Structure and Electrochemical Properties of Cathode Materials (Na3V2 ‒ xScx(PO4)3) for Sodium-Ion Batteries
- Авторлар: Perfilyeva T.1, Alekseeva A.1, Drozhzhin O.1, Antipov E.1,2
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Мекемелер:
- Faculty of Chemistry, Moscow State University
- Skolkovo Institute of Science and Technology
- Шығарылым: Том 59, № 7 (2023)
- Беттер: 369-377
- Бөлім: Articles
- URL: https://journals.rcsi.science/0424-8570/article/view/139287
- DOI: https://doi.org/10.31857/S0424857023070095
- EDN: https://elibrary.ru/TXUCTA
- ID: 139287
Дәйексөз келтіру
Аннотация
Solid solutions Na3V2 − xScx(PO4)3 (0 < x < 2) are synthesized by the sol-gel method followed by annealing in inert atmosphere. The structure of Na3V2 − xScx(PO4)3 (x = 0.5, 1.2) compounds is studied by the method of powder X-ray diffraction. As the degree of substitution increases, the unit cell parameters and volume tend to increase on retention of the NASICON-type structure. The electrochemical properties of Na3V2 − xScx(PO4)3/C materials as the cathodes for sodium-ion batteries are studied in sodium half-cells in different potential intervals: 2.5−3.8, 2.5−4.5, and 1.0−4.5 V vs. Na/Na+. The charging curves of all materials demonstrate two plateaus: at ≈3.5 and ≈4 V vs. Na/Na+, corresponding to the successive transitions V3+/V4+ and V4+/V5+. However, the high-voltage plateau is reversible at the subsequent discharge only for the Na3V1.5Sc0.5(PO4)3/C material. This allows one to carry out the stable reversible cycling of this material in the potential interval of 1.0−4.5 V vs. Na/Na+ with the capacity higher than 170 mA h g−1, which corresponds to (de)intercalation of three Na+ per formula unit.
Негізгі сөздер
Авторлар туралы
T. Perfilyeva
Faculty of Chemistry, Moscow State University
Email: tatjana.perf@yandex.ru
Moscow, Russia
A. Alekseeva
Faculty of Chemistry, Moscow State University
Email: tatjana.perf@yandex.ru
Moscow, Russia
O. Drozhzhin
Faculty of Chemistry, Moscow State University
Email: tatjana.perf@yandex.ru
Moscow, Russia
E. Antipov
Faculty of Chemistry, Moscow State University; Skolkovo Institute of Science and Technology
Хат алмасуға жауапты Автор.
Email: tatjana.perf@yandex.ru
Moscow, Russia; Moscow, Russia
Әдебиет тізімі
- Tsiropoulos, I., Tarvydas, D., and Lebedeva, N., EUR 29440 EN, Li-ion batteries for mobility and stationary storage applications Scenarios for costs and market growth, Publications Office of the European Union, Luxembourg, 2018, p. 67.
- Vaalma, C., Buchholz, D., Weil, M., and Passerini, S., A cost and resource analysis of sodium-ion batteries, Nat. Rev. Mater., 2018, vol. 3, p. 18013.
- Rajagopalan, R., Zhang, Z., Tang Y., Jia, C., Xiaobo, Ji, and Wang, H., Understanding crystal structures, ion diffusion mechanisms and sodium storage behaviors of NASICON materials, Energy Storage Materials, 2021, vol. 34, p. 171.
- Hong, H.Y.-P., Crystal structures and crystal chemistry in the system Na1 + xZr2SixP3 – xO12, Mater. Res. Bull., 1976, vol. 11, p. 173.
- Goodenough, J.B., Hong H.Y.P., and Kafalas, J., Fast Na+-ion transport in skeleton structures, Mater. Res. Bull., 1976, vol. 11, p. 203.
- Rajagopalan, R., Chen, B., Zhang, Z., Wu, X.-L., Du, Y. Huang, B., Li, Y., Zong, J., Wang, G.-H., Nam, M., Sindoro, S.X., Dou, H.K., Liu, H., Zhang, Improved Reversibility of Fe3+/Fe4+Redox Couple in Sodium Super Ion Conductor Type Na3Fe2(PO4)3 for Sodium-Ion Batteries, Adv. Mater., 2017, vol. 29, p. 1605694.
- Samigullin, R., Drozhzhin, O., and Antipov, E., Comparative Study of the Thermal Stability of Electrode Materials for Li-Ion and Na-Ion Batteries, ACS Appl. Energy Mater., 2022, vol. 5, p. 14.
- Wang, J., Wang, Y., Seo, D., Shi, T., Chen, S., Tian, Y., Kim, H., and Ceder, G., A High-Energy NASICON-Type Cathode Material for Na-Ion Batteries, Adv. Energy Mater., 2020, vol. 10, p. 1903968.
- Zhang, X., Rui, X., Chen, D., Tan, H., Yang, D., Huang, S., and Yu Y., Na3V2(PO4)3: an advanced cathode for sodium-ion batteries, Nanoscale, 2019, vol. 11, p. 2556.
- Saravanan, K., Mason, C., Rudola, A., Wong, K., and Balaya, P., The First Report on Excellent Cycling Stability and Superior Rate Capability of Na3V2(PO4)3for Sodium Ion Batteries, Adv. Energy Mater., 2013, vol. 3, p. 444.
- Jian, Z., Sun, Y., and Ji, X., A new low-voltage plateau of Na3V2(PO4)3as an anode for Na-ion batteries, Chem. Commun., 2015, vol. 51, p. 6381.
- Jian, Z., Han, W., Lu, X., Yang, H., Hu, Y.-S., Zhou, J., Zhou, Z., Li, J., Chen, W., Chen, D., and Chen, L., Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries, Energy Mater., 2013, vol. 3, p. 156.
- Zhou, W., Xue, L., Lu, X., Gao, H., Li, Y., Xin, S., Fu, G., Cui, Z., Zhu, Y., and Goodenough, J., NaxMV(PO4)3 (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction, J. Amer. Chem. Soc., 2016, vol. 16, p. 7836.
- Zakharkin, M., Drozhzhin, O., Tereshchenko, I., Chernyshov, D., Abakumov, A., Antipov, E., and Stevenson, K., Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode, ACS Appl. Energy Mater., 2018, vol. 1, p. 5842.
- Zakharkin, M., Drozhzhin, O., Ryazantsev, S., Chernyshov, D., Kirsanova,M., Mikheev, I., Pazhetnov, E., Antipov, E., and Stevenson, K., Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na3 + xMnxV2 – x(PO4)3(0 ≤ ≤ x ≤ 1) cathodes for Na-ion batteries, J. Power Sources., 2020, vol. 470, p. 228231.
- Aragón, M.J., Lavela, P., Alcántara, R., and Tirado, J.L., Effect of aluminum doping on carbon loaded Na3V2(PO4)3as cathode material for sodium-ion batteries, Electrochim. Acta, 2015, vol. 180, p. 824.
- Wang, Q., Zhao, Y., Gao, J., Geng, H., Li, J., and Jin, H., Triggering the Reversible Reaction of V3+/V4+/V5+in Na3V2(PO4)3by Cr3+ Substitution, ACS Appl. Mater. Interfaces, 2020, vol. 12, p. 50315.
- Liu, R., Xu, G., Li, Q., Zheng, S., Zheng, G., Gong, Z., Li, Y., Kruskop, E., Fu, R., Chen, Z., Amine, K., and Yang, Y., Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries, ACS Appl. Mater. Interfaces, 2017, vol. 9, p. 43639.
- Lalère, F., Seznec, V., Courty, M., David, R., Chotard, J.N., and Masquelier, C., Improving the energy density of Na3V2(PO4)3-based positive electrodes through V/Al substitution, J. Mater. Chem. A, 2015, vol. 3, p. 16198.
- Inoishi, A., Yoshioka, Y., Zhao, L., Kitajou, A., and Okada, S., Improvement in the Energy Density of Na3V2(PO4)3 by Mg Substitution, ChemElectroChem, 2017, vol. 4, p. 2755.
- Singh, B., Wang, Z., Park, S., Sai Gautam, G., Chotard, J.-N., Croguennec, L., Carlier, D., Cheetham, A.K., Masquelier, C., and Canepa P., A Chemical Map of NASICON Electrode Materials for Sodium-ion Batteries, J. Mater. Chem. A, 2021, vol. 9, p. 281.
- Boivin, E., Chotard, J.-N., Masquelier, C., and Croguennec, L., Towards Reversible High-Voltage Multi-Electron Reactions in Alkali-Ion Batteries Using Vanadium Phosphate Positive Electrode Materials, Molecules, 2021, vol. 26, p. 1428.
- Perfilyeva, T., Drozhzhin, O., Alekseeva, A., Zakharkin, M., Mironov, A., Mikheev, I., Bobyleva, Z., Marenko, A., Marikutsa, A., Abakumov, A., and Antipov, E., Complete Three-Electron Vanadium Redox in NASICON-Type Na3VSc(PO4)3 Electrode Material for Na-Ion Batteries, J. Electrochem. Soc., 2021, vol. 168, p. 110550.
- Shannon, R., Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides, ActaCryst., 1976, vol. A32, p. 751.
- STOE Win XPOW, Version 1.2 (27-Jul-2001), 2000 STOE, Cie GmbH, Hilpert str. 10, D64295 Darmstadt.
- Petrícek, V., Dušek, M., and Palatinus, L., Crystallographic computing system JANA2006: General features, Zeitschrift fur Krist., 2014, vol. 229, p. 345.
- ICDD PDF-2, International Center for Diffraction Data, Newton Square, USA, 1998.
- ICDD PDF-4+, International Center for Diffraction Data, Newton Square, USA, 2020.
- Jian, Z., Zhao, L., Hu, Y.-S., Li, H., Chen, W., and Chen, L., Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries, Electrochem. Commun., 2012, vol. 14, p. 86.
- Liu, R., Zheng, S., Yuan, Y., Yu, P., Liang, Z., and Zhao, W., Counter-Intuitive Structural Instability Aroused by Transition Metal Migration in Polyanionic Sodium Ion Host, Adv. Energy Mater., 2021, vol. 11, p. 2003256.
- Kim, S., Zhang, Z., Wang, S., Yang, L., Cairns, E.J., Penner-Hahn, J.E., and Deb, A., Electrochemical and Structural Investigation of the Mechanism of Irreversibility in Li3V2(PO4)3 Cathodes, J. Phys. Chem. C, 2016, vol. 120, p. 7005.