Lanthanum Propionate Monohydrate and Its Mixed-Ligand Complex with Diethylenetriamine: Synthesis, Crystal Structure, and Use in Chemical Solution Deposition of Lanthanum Nickelate Thin Films

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A mixed-ligand complexation approach implying the reaction of metal carboxylates with the chelating tridendate diethylenetriamine (DETA) ligand has been applied to modify the structure of the layered coordination polymer based on lanthanum propionate (Prop). Lanthanum propionate monohydrate has been synthesized and characterized by a set of analytical methods to determine its crystal structure and chemical composition. The crystal structures of lanthanum propionate and nickel propionate complexes with DETA have additionally been determined. The native lanthanum propionate monohydrate [La2(H2O)2Prop6] has been proven to have a 2D-layered topology, whereas the mixed-ligand complex [La2(DETA)Prop6] ⋅ MeCN (where MeCN stands for acetonitrile) has a chain structure. A chemical solution deposition procedure has been developed to produce phase-pure oriented LaNiO3 thin films. These films exhibit metallic conductivity and can be used as conductive sublayers.

作者简介

M. Kendin

Chemistry Department, Moscow State University; Materials Science Department, Moscow State University

Email: tsymbarenko@gmail.com
119991, Moscow, Russia; 119991, Moscow, Russia

R. Gashigullin

Materials Science Department, Moscow State University

Email: tsymbarenko@gmail.com
119991, Moscow, Russia

I. Martynova

Chemistry Department, Moscow State University

Email: tsymbarenko@gmail.com
119991, Moscow, Russia

A. Anosov

Chemistry Department, Moscow State University; Materials Science Department, Moscow State University

Email: tsymbarenko@gmail.com
119991, Moscow, Russia; 119991, Moscow, Russia

D. Tsymbarenko

Chemistry Department, Moscow State University

编辑信件的主要联系方式.
Email: tsymbarenko@gmail.com
119991, Moscow, Russia

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版权所有 © М.П. Кендин, Р.А. Гашигуллин, И.А. Мартынова, А.А. Аносов, Д.М. Цымбаренко, 2023

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