Lanthanum Propionate Monohydrate and Its Mixed-Ligand Complex with Diethylenetriamine: Synthesis, Crystal Structure, and Use in Chemical Solution Deposition of Lanthanum Nickelate Thin Films
- Authors: Kendin M.P.1,2, Gashigullin R.A.2, Martynova I.A.1, Anosov A.A.1,2, Tsymbarenko D.M.1
-
Affiliations:
- Chemistry Department, Moscow State University
- Materials Science Department, Moscow State University
- Issue: Vol 68, No 9 (2023)
- Pages: 1293-1302
- Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://journals.rcsi.science/0044-457X/article/view/136498
- DOI: https://doi.org/10.31857/S0044457X2360113X
- EDN: https://elibrary.ru/WODXEF
- ID: 136498
Cite item
Abstract
A mixed-ligand complexation approach implying the reaction of metal carboxylates with the chelating tridendate diethylenetriamine (DETA) ligand has been applied to modify the structure of the layered coordination polymer based on lanthanum propionate (Prop). Lanthanum propionate monohydrate has been synthesized and characterized by a set of analytical methods to determine its crystal structure and chemical composition. The crystal structures of lanthanum propionate and nickel propionate complexes with DETA have additionally been determined. The native lanthanum propionate monohydrate [La2(H2O)2Prop6] has been proven to have a 2D-layered topology, whereas the mixed-ligand complex [La2(DETA)Prop6] ⋅ MeCN (where MeCN stands for acetonitrile) has a chain structure. A chemical solution deposition procedure has been developed to produce phase-pure oriented LaNiO3 thin films. These films exhibit metallic conductivity and can be used as conductive sublayers.
Keywords
About the authors
M. P. Kendin
Chemistry Department, Moscow State University; Materials Science Department, Moscow State University
Email: tsymbarenko@gmail.com
119991, Moscow, Russia; 119991, Moscow, Russia
R. A. Gashigullin
Materials Science Department, Moscow State University
Email: tsymbarenko@gmail.com
119991, Moscow, Russia
I. A. Martynova
Chemistry Department, Moscow State University
Email: tsymbarenko@gmail.com
119991, Moscow, Russia
A. A. Anosov
Chemistry Department, Moscow State University; Materials Science Department, Moscow State University
Email: tsymbarenko@gmail.com
119991, Moscow, Russia; 119991, Moscow, Russia
D. M. Tsymbarenko
Chemistry Department, Moscow State University
Author for correspondence.
Email: tsymbarenko@gmail.com
119991, Moscow, Russia
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