Investigation of the effect of scandium concentration in the oxide composition Y2O3–Sc2O3–Al2O3–Er2O3 on the thermophysical properties of optical ceramics

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Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The influence of the concentration and position of scandium cations on the thermophysical characteristics of optical ceramics based on a solid solution of Y2O3–Er2O3–Sc2O3–Al2O3 oxides with a garnet structure has been studied. It is established that an increase in the total concentration of scandium leads to a decrease in the thermal conductivity coefficient in ceramics. The dependences of the thermal conductivity coefficient on the concentration and position of scandium cations in the garnet lattice are obtained. As a result the decrease in thermal conductivity of ceramics based on yttrium-erbium-scandium-aluminum garnet is due to structural disordering associated with partial substitution of cations in six- and eight-coordinate positions in the garnet lattice.

Толық мәтін

Рұқсат жабық

Авторлар туралы

I. Chikulina

North-Caucasus Federal University

Email: ichikulina@ncfu.ru
Ресей, Stavropol, 355009

D. Vakalov

North-Caucasus Federal University

Email: ichikulina@ncfu.ru
Ресей, Stavropol, 355009

S. Kichuk

North-Caucasus Federal University

Email: ichikulina@ncfu.ru
Ресей, Stavropol, 355009

V. Tarala

North-Caucasus Federal University

Email: ichikulina@ncfu.ru
Ресей, Stavropol, 355009

F. Malyavin

International Research Technological University “MISIS”

Email: ichikulina@ncfu.ru
Ресей, Moscow, 119991

L. Kozhitov

International Research Technological University “MISIS”

Хат алмасуға жауапты Автор.
Email: ichikulina@ncfu.ru
Ресей, Moscow, 119991

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2. Fig. 1. Diffraction patterns of ceramic powders of samples ES1–ES6, calcined at a temperature of 1100C.

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3. Fig. 2. SEM image of sample ES6 calcined at 1100°C.

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4. Fig. 3. Microphotographs of the surface of YErSAG optical ceramics.

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5. Fig. 4. Optical transmission spectra of YErSAG ceramics and the appearance of the resulting samples (in the insets).

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6. Fig. 5. Temperature dependences of the thermophysical characteristics of YErSAG optical ceramics: specific heat (a), thermal diffusivity (b) and thermal conductivity (c).

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7. Fig. 6. Dependence of the thermal conductivity of YErSAG optical ceramics on the Sc3+ concentration: in the dodecahedral position (a), in the octahedral position (b) and total (c).

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8. Fig. 7. Dependence of the thermal conductivity of YErSAG optical ceramics on the value of the dimensional disorder coefficient.

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