Investigation of the effect of scandium concentration in the oxide composition Y2O3–Sc2O3–Al2O3–Er2O3 on the thermophysical properties of optical ceramics
- Authors: Chikulina I.S.1, Vakalov D.S.1, Kichuk S.N.1, Tarala V.A.1, Malyavin F.F.2, Kozhitov L.V.2
-
Affiliations:
- North-Caucasus Federal University
- International Research Technological University “MISIS”
- Issue: Vol 69, No 1 (2024)
- Pages: 49-57
- Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
- URL: https://journals.rcsi.science/0044-457X/article/view/257697
- DOI: https://doi.org/10.31857/S0044457X24010065
- EDN: https://elibrary.ru/ZZSDUE
- ID: 257697
Cite item
Abstract
The influence of the concentration and position of scandium cations on the thermophysical characteristics of optical ceramics based on a solid solution of Y2O3–Er2O3–Sc2O3–Al2O3 oxides with a garnet structure has been studied. It is established that an increase in the total concentration of scandium leads to a decrease in the thermal conductivity coefficient in ceramics. The dependences of the thermal conductivity coefficient on the concentration and position of scandium cations in the garnet lattice are obtained. As a result the decrease in thermal conductivity of ceramics based on yttrium-erbium-scandium-aluminum garnet is due to structural disordering associated with partial substitution of cations in six- and eight-coordinate positions in the garnet lattice.
Full Text
About the authors
I. S. Chikulina
North-Caucasus Federal University
Email: ichikulina@ncfu.ru
Russian Federation, Stavropol, 355009
D. S. Vakalov
North-Caucasus Federal University
Email: ichikulina@ncfu.ru
Russian Federation, Stavropol, 355009
S. N. Kichuk
North-Caucasus Federal University
Email: ichikulina@ncfu.ru
Russian Federation, Stavropol, 355009
V. A. Tarala
North-Caucasus Federal University
Email: ichikulina@ncfu.ru
Russian Federation, Stavropol, 355009
F. F. Malyavin
International Research Technological University “MISIS”
Email: ichikulina@ncfu.ru
Russian Federation, Moscow, 119991
L. V. Kozhitov
International Research Technological University “MISIS”
Author for correspondence.
Email: ichikulina@ncfu.ru
Russian Federation, Moscow, 119991
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