Microwave-Assisted Hydrothermal Synthesis of Ceric-Ammonium Phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3

I. V. Tronev; Тронев И. В.; E. D. Sheichenko; Шейченко Е. Д.; L. S. Razvorotneva; Разворотнева Л. С.; E. A. Trufanova; Труфанова Э. А.; P. V. Minakova; Минакова П. В.; T. O. Kozlova; Козлова Т. О.; A. E. Baranchikov; Баранчиков А. Е.; V. K. Ivanov; Иванов В. К.

doi:10.31857/S0044457X22601869

Microwave-Assisted Hydrothermal Synthesis of Ceric-Ammonium Phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3

Авторлар: Tronev I.¹^,2, Sheichenko E.¹^,2, Razvorotneva L.¹^,2, Trufanova E.¹^,2, Minakova P.¹^,2, Kozlova T.¹, Baranchikov A.¹, Ivanov V.¹^,2
Мекемелер:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. National Research University Higher School of Economics
Шығарылым: Том 68, № 3 (2023)
Беттер: 318-324
Бөлім: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/136328
DOI: https://doi.org/10.31857/S0044457X22601869
EDN: https://elibrary.ru/JEWBVV
ID: 136328

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Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

The possibility of preparation of crystalline double cerium(IV) phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3 under the conditions of microwave-assisted hydrothermal synthesis has been analyzed. It has been shown that these phosphates in a single-phase state can be obtained in the temperature range of 130–190°С with a synthesis duration of ≥5 min, while the phase composition of the synthesis products is determined by the molar ratio of ammonia and phosphoric acid in the reaction mixture. Short-term (5 min) low-temperature (130°С) hydrothermal synthesis under microwave heating leads to the preparation of (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3 with a particle size of ~70 and ~200 nm, respectively. At higher temperatures and treatment times (190°C and 24 h), the particle size of these phases increases to ~200 and ~500 nm, respectively. For the first time, the value of the optical band gap for (NH4)2Ce(PO4)2⋅H2O was determined to be 2.8 and 3.1 eV for indirect and direct transitions, respectively.

Негізгі сөздер

phosphates, REE, cerium, hydrothermal treatment

Әдебиет тізімі

Nazaraly M., Wallez G., Chanéac C. et al. // Angew. Chem. Int. Ed. 2005. V. 44. P. 5691. https://doi.org/10.1002/anie.200501871
Nazaraly M., Wallez G., Chanéac C. et al. // J. Phys. Chem. Solids. 2006. V. 67. P. 1075. https://doi.org/10.1016/j.jpcs.2006.01.028
Козлова Т.О., Баранчиков А.Е., Иванов В.К. // Журн. неорган. химии. 2021. Т. 66. № 12. С. 1647. https://doi.org/10.31857/s0044457x21120102
Bevara S., Achary S.N., Patwe S.J. et al. // AIP Conf. Proc. 2016. V. 1731. P. 1. https://doi.org/10.1063/1.4948206
Nazaraly M., Quarton M., Wallez G. et al. // Solid State Sci. 2007. V. 9. P. 672. https://doi.org/10.1016/j.solidstatesciences.2007.04.021
Achary S.N., Bevara S., Tyagi A.K. // Coord. Chem. Rev. 2017. V. 340. № March. P. 266. https://doi.org/10.1016/j.ccr.2017.03.006
Romanchuk A.Y., Shekunova T.O., Larina A.I. et al. // Radiochemistry. 2019. V. 61. № 6. P. 719. https://doi.org/10.1134/S1066362219060134
Sato T., Li R., Sato C. et al. // Phosphorus Res. Bull. 2007. V. 21. P. 44. https://doi.org/10.3363/prb.21.44
Sato T., Yin S. // Phosphorus Res. Bull. 2010. V. 24. P. 43. https://doi.org/10.3363/prb.24.43
Sato T., Sato C., Yin S. // Phosphorus Res. Bull. 2008. V. 22. P. 17. https://doi.org/10.3363/prb.22.17
Kozlova T.O., Popov A.L., Kolesnik I.V. et al. // J. Mater. Chem. B. 2022. V. 10. № 11. P. 1775. https://doi.org/10.1039/d1tb02604f
Nazaraly M., Chanéac C., Ribot F. et al. // J. Phys. Chem. Solids. 2007. V. 68. P. 795. https://doi.org/10.1016/j.jpcs.2007.03.010
Shekunova T.O., Istomin S.Y., Mironov A.V. et al. // Eur. J. Inorg. Chem. 2019. V. 2019. № 27. P. 3242. https://doi.org/10.1002/ejic.201801182
Kozlova T.O., Mironov A.V., Istomin S.Y. et al. // Chem. A Eur. J. 2020. V. 26. № 53. P. 12188. https://doi.org/10.1002/chem.202002527
Lai Y., Chang Y., Wong T. et al. // Inorg. Chem. 2013. V. 52. № 23. P. 13639.
Salvado M.A., Pertierra P., Trobajo C. et al. // J. Am. Chem. Soc. 2007. V. 129. № 36. P. 10970.
Shekunova T.O., Baranchikov A.E., Ivanova O.S. et al. // J. Non-Cryst. Solids. 2016. V. 447. P. 183. https://doi.org/10.1016/j.jnoncrysol.2016.06.012
Zhu Y.J., Chen F. // Chem. Rev. 2014. V. 114. № 12. P. 6462. https://doi.org/10.1021/cr400366s
Meng L.Y., Wang B., Ma M.G. et al. // Mater. Today Chem. 2016. V. 1–2. P. 63. https://doi.org/10.1016/j.mtchem.2016.11.003
Moreira M.L., Mambrini G.P., Volanti D.P. et al. // Chem. Mater. 2008. V. 20. № 16. P. 5381. https://doi.org/10.1021/cm801638d
Salvadó M.A., Pertierra P., Bortun A.I. et al. // Inorg. Chem. 2008. V. 47. № 16. P. 7207. https://doi.org/10.1021/ic800818c
Petit S., Righi D., Madejová J. // Appl. Clay Sci. 2006. V. 34. № 1–4. P. 22. https://doi.org/10.1016/j.clay.2006.02.007
Petit S., Righi D., Madejová J. et al. // Clay Miner. 1999. V. 34. P. 543.
Kloprogge J.T., Broekmans M., Duong L.V. et al. // J. Mater. Sci. 2006. V. 41. № 11. P. 3535. https://doi.org/10.1007/s10853-005-5909-5
Xu Y., Feng S., Pang W. et al. // Chem. Commun. 1996. № 11. P. 1305. https://doi.org/10.1039/CC9960001305
Brandel V., Clavier N., Dacheux N. // J. Solid State Chem. 2005. V. 178. № 4. P. 1054. https://doi.org/10.1016/j.jssc.2005.01.005
Skogareva L.S., Shekunova T.O., Baranchikov A.E. et al. // Russ. J. Inorg. Chem. 2016. V. 61. № 10. P. 1219. https://doi.org/10.1134/S0036023616100181
Hadrich A., Lautie A., Mhiri T. et al. // Vib. Spectrosc. 2001. V. 26. P. 51.
Yang G., Park S.-J. // Materials (Basel). 2019. V. 12. № 7. P. 1177. https://doi.org/10.3390/ma12071177
Maksimov V.D., Meskin P.E., Churagulov B.R. // Inorg. Mater. 2007. V. 43. № 9. P. 988. https://doi.org/10.1134/S0020168507090142
Zhou H., Zhang M., Kong S. et al. // Mater. Lett. 2016. V. 180. P. 239. https://doi.org/10.1016/j.matlet.2016.05.165
Qi C., Zhu Y.-J., Sun T.-W. et al. // Chem. An Asian J. 2015. V. 10. № 11. P. 2503. https://doi.org/10.1002/asia.201500667
Sakintuna B., Yürüm Y. // J. Porous Mater. 2010. V. 17. № 6. P. 727. https://doi.org/10.1007/s10934-009-9344-x
Yu Y.-H., Chen Y.-P., Zeng M. et al. // Mater. Lett. 2016. V. 163. P. 158. https://doi.org/10.1016/j.matlet.2015.10.039
Kolesnik I.V., Aslandukov A.N., Arkhipin A.S. et al. // Crystals. 2019. V. 9. № 7. P. 332. https://doi.org/10.3390/cryst9070332